Is the computed speciation of copper in a wide range of Chinese soils reliable?
文献类型：期刊论文
| 作者 | Li, Bo1; Ma, Yibing2; Yang, Junxing3
|
| 刊名 | CHEMICAL SPECIATION AND BIOAVAILABILITY
 |
| 出版日期 | 2017-11-22 |
| 卷号 | 29期号:1页码:205-215 |
| 关键词 | Copper activity soil pore water distribution model prediction |
| ISSN号 | 0954-2299 |
| DOI | 10.1080/09542299.2017.1404437 |
| 通讯作者 | Ma, Yibing(ybma@caas.ac.cn) |
| 英文摘要 | Free Cu species in soils is a key issue to its bioavailability. However, predictive models for Cu speciation across a wide range of soils were still unavailable. In this study, Cu speciation in 34 contaminated soil samples were investigated via analytical technique and predictive models. The results showed that most of free Cu2+ was underestimated when using default log K-CuFA and 65% active fulvic acid as inputs in models of WHAM VI and NICA-Donnan. The best prediction was found when using either adjusted active fulvic acid from 10% to 125% for WHAM VI or from 15% to 65% for NICA-Donnan model with the RMSE < 0.32 and r(2) > 0.96. In contrast, NICA-Donnan demonstrated a slightly stronger binding for Cu than WHAM VI due to extra 26% of samples was underestimated. This work presents a comprehensive database of Cu speciation and an effective attempt of free Cu2+ prediction in a wide range of Chinese soils. |
| WOS关键词 | DISSOLVED ORGANIC-MATTER ; DONNAN MEMBRANE TECHNIQUE ; ION-SELECTIVE ELECTRODE ; CONTAMINATED SOILS ; METAL SPECIATION ; HEAVY-METALS ; NICA-DONNAN ; EQUILIBRIUM MODEL ; HUMIC SUBSTANCES ; NATURAL-WATERS |
| 资助项目 | Natural Science Foundation of China[41401361] ; project of Research on Migration/Transformation and Safety Threshold of Heavy Metals in Farmland Systems[2016YFD0800406] ; Natural Science Foundation of Liaoning Province[2015020584] ; GDAS |
| WOS研究方向 | Biochemistry & Molecular Biology ; Environmental Sciences & Ecology ; Toxicology |
| 语种 | 英语 |
| WOS记录号 | WOS:000423056200001 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 资助机构 | Natural Science Foundation of China ; project of Research on Migration/Transformation and Safety Threshold of Heavy Metals in Farmland Systems ; Natural Science Foundation of Liaoning Province ; GDAS |
| 源URL | [http://ir.igsnrr.ac.cn/handle/311030/60540]  |
| 专题 | 中国科学院地理科学与资源研究所 |
| 通讯作者 | Ma, Yibing |
| 作者单位 | 1.Liaoning Acad Agr Sci, Inst Plant Nutr & Environm Resources, Shenyang, Liaoning, Peoples R China 2.Chinese Acad Agr Sci, Inst Agr Resources & Reg Planning, Natl Soil Fertil & Fertilizer Effects Long Term M, Beijing, Peoples R China 3.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, Ctr Environm Remediat, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Bo,Ma, Yibing,Yang, Junxing. Is the computed speciation of copper in a wide range of Chinese soils reliable?[J]. CHEMICAL SPECIATION AND BIOAVAILABILITY,2017,29(1):205-215. |
| APA | Li, Bo,Ma, Yibing,&Yang, Junxing.(2017).Is the computed speciation of copper in a wide range of Chinese soils reliable?.CHEMICAL SPECIATION AND BIOAVAILABILITY,29(1),205-215. |
| MLA | Li, Bo,et al."Is the computed speciation of copper in a wide range of Chinese soils reliable?".CHEMICAL SPECIATION AND BIOAVAILABILITY 29.1(2017):205-215. |
入库方式： OAI收割
来源：地理科学与资源研究所
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