Pattern-Based Recognition for Determination of Enantiomeric Excess, Using Chiral Auxiliary Induced Chemical Shift Perturbation NMR
文献类型：期刊论文
| 作者 | Lei, Xinxiang ; Liu, Lu ; Chen, Xiaojing ; Yu, Xiaochun ; Ding, Lisheng ; Zhang, Anjiang |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2010 |
| 卷号 | 12期号:11页码:2540-2543 |
| ISSN号 | 1523-7060 |
| 产权排序 | 2 |
| 通讯作者 | Lei, XX, Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China |
| 中文摘要 | A protocol for the determination of enantiomeric excess of chiral carboxylic acid, using the subtle frequency shifts (chemical shift perturbation) in NMR spectra induced by chiral auxiliary, is described. The spectra were analyzed with two pattern recognition protocols. Principal component analysis demonstrated good enantioselective separation of the analytes, and partial least-squares was used to analyze ee values of unknown samples. |
| 学科主题 | Chemistry, Organic |
| 收录类别 | SCI |
| 资助信息 | NSFC [30900129]; ZJNSFC [Y2080331]; ZJST [2009C34014]; WZST [H20080052] |
| 语种 | 英语 |
| WOS记录号 | WOS:000278062600026 |
| 公开日期 | 2011-07-08 |
| 源URL | [http://210.75.237.14/handle/351003/18419]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Lei, Xinxiang,Liu, Lu,Chen, Xiaojing,et al. Pattern-Based Recognition for Determination of Enantiomeric Excess, Using Chiral Auxiliary Induced Chemical Shift Perturbation NMR[J]. ORGANIC LETTERS,2010,12(11):2540-2543. |
| APA | Lei, Xinxiang,Liu, Lu,Chen, Xiaojing,Yu, Xiaochun,Ding, Lisheng,&Zhang, Anjiang.(2010).Pattern-Based Recognition for Determination of Enantiomeric Excess, Using Chiral Auxiliary Induced Chemical Shift Perturbation NMR.ORGANIC LETTERS,12(11),2540-2543. |
| MLA | Lei, Xinxiang,et al."Pattern-Based Recognition for Determination of Enantiomeric Excess, Using Chiral Auxiliary Induced Chemical Shift Perturbation NMR".ORGANIC LETTERS 12.11(2010):2540-2543. |
入库方式： OAI收割
来源：成都生物研究所
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