中国科学院机构知识库网格系统: Development of new method for D/H ratio measurements for volatile hydrocarbons of crude oils using solid phase micro-extraction (SPME) coupled to gas chromatography isotope ratio mass spectrometry (GC-IRMS)

Development of new method for D/H ratio measurements for volatile hydrocarbons of crude oils using solid phase micro-extraction (SPME) coupled to gas chromatography isotope ratio mass spectrometry (GC-IRMS)

文献类型：期刊论文


作者	Li, Zhongping 1,2,3,4; Li, Liwu 3,4; Xing, Lantian 3,4; Liu, Yan 3,4; Zhang, Mingjie 1,2; Wang, Xibin 3,4; Cao, Chunhui 3,4; Wang, Zuodong 3,4
刊名	MARINE AND PETROLEUM GEOLOGY
出版日期	2018
卷号	89 页码:232-241
关键词	Solid Phase Microextraction (Spme) Gas Chromatography(Gc) Hydrogen Isotope Ratio Isotope Ratio Mass-spectrometry(Irms) Trace Hydrocarbons Crude Oils
ISSN号	0264-8172
DOI	10.1016/j.marpetgeo.2017.01.008
文献子类	Article
英文摘要	In compound-specific isotope analysis (CSIA), one major challenge is the effective sample treatment and the isolation of sufficient amount of analytes for accurate measurements for isotope ratios. The hydrogen isotope ratio (D/H) of normal level hydrocarbons in crude oils has been successfully used as an isotopic tracer in oil-oil and oil-gas correlations, but little progress so far has been made for small size hydrocarbons (C-6-C-15). In this paper, we presented a novel method for sample treatment and achieved the D/H ratio analysis for these particular compounds. The method can be characterized as an efficient approach featured by SPME (solid phase micro-extraction) coupled to GC-IRMS (gas chromatography-isotope ratio mass spectrometry). In this investigation, the CAR/DVB/PDMS fiber was evaluated and used as the absorptive material, and the operating conditions, including the extraction time (0.1 min-150 min) and the extraction temperature (-30 degrees C-140 degrees C), which may affect the adsorption amount, were carefully evaluated, and it was found that the adsorption yields varied considerably not only with the operating conditions but also with the molecular size. In addition, the possible hydrogen isotopic fractionation, which may exert strong influence on D/H ratios, were also discussed, it was found that the hydrogen isotopic fractionation were not observed in the extraction process, and the D/H ratios obtained via SPME-GC/IRMS were in good agreement with the EA-IRMS. Notably, the difference between the two approaches was generally within the expected uncertainties from 0.8 parts per thousand to 4.2 parts per thousand, indicating the method is high efficient for volatile hydrocarbon enrichments and the D/H measurements. To assess the validity of the established method, one typical crude oil sample was analyzed, and the D/H ratio results displayed considerable large variation, enough to distinguished between different compounds, showing the established method is well suited for trace hydrocarbon enrichment, and provides so far the most efficient and reliable means for D/H analysis. (C) 2017 Elsevier Ltd. All rights reserved.
WOS关键词	N-ALKANES ; STABLE CARBON ; PETROLEUM CONTAMINATION ; FATTY-ACID ; MICROEXTRACTION ; SAMPLES ; SEDIMENTS ; BASIN ; MS ; DELTA-C-13
WOS研究方向	Geology
语种	英语
WOS记录号	WOS:000418976800023
出版者	ELSEVIER SCI LTD
资助机构	National Science Foundation(41272145 ; National Science Foundation(41272145 ; West Light Foundation of Chinese Academy of Sciences ; West Light Foundation of Chinese Academy of Sciences ; 41572136) ; 41572136) ; National Science Foundation(41272145 ; National Science Foundation(41272145 ; West Light Foundation of Chinese Academy of Sciences ; West Light Foundation of Chinese Academy of Sciences ; 41572136) ; 41572136) ; National Science Foundation(41272145 ; National Science Foundation(41272145 ; West Light Foundation of Chinese Academy of Sciences ; West Light Foundation of Chinese Academy of Sciences ; 41572136) ; 41572136) ; National Science Foundation(41272145 ; National Science Foundation(41272145 ; West Light Foundation of Chinese Academy of Sciences ; West Light Foundation of Chinese Academy of Sciences ; 41572136) ; 41572136)
源URL	[http://ir.iggcas.ac.cn/handle/132A11/93140]
专题	地质与地球物理研究所_兰州油气中心
通讯作者	Li, Zhongping
作者单位	1.Lanzhou Univ, Sch Earth Sci, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Univ, Gansu Key Lab Mineral Resources Western China, Lanzhou 730000, Gansu, Peoples R China 3.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Petr Resources Res, Lanzhou 730000, Gansu, Peoples R China 4.Chinese Acad Sci, Northwest Inst Ecoenvironm & Resources, Res Ctr Oil & Gas Resources, Lanzhou 730000, Gansu, Peoples R China
推荐引用方式 GB/T 7714	Li, Zhongping,Li, Liwu,Xing, Lantian,et al. Development of new method for D/H ratio measurements for volatile hydrocarbons of crude oils using solid phase micro-extraction (SPME) coupled to gas chromatography isotope ratio mass spectrometry (GC-IRMS)[J]. MARINE AND PETROLEUM GEOLOGY,2018,89:232-241.
APA	Li, Zhongping.,Li, Liwu.,Xing, Lantian.,Liu, Yan.,Zhang, Mingjie.,...&Wang, Zuodong.(2018).Development of new method for D/H ratio measurements for volatile hydrocarbons of crude oils using solid phase micro-extraction (SPME) coupled to gas chromatography isotope ratio mass spectrometry (GC-IRMS).MARINE AND PETROLEUM GEOLOGY,89,232-241.
MLA	Li, Zhongping,et al."Development of new method for D/H ratio measurements for volatile hydrocarbons of crude oils using solid phase micro-extraction (SPME) coupled to gas chromatography isotope ratio mass spectrometry (GC-IRMS)".MARINE AND PETROLEUM GEOLOGY 89(2018):232-241.

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来源：地质与地球物理研究所

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Development of new method for D/H ratio measurements for volatile hydrocarbons of crude oils using solid phase micro-extraction (SPME) coupled to gas chromatography isotope ratio mass spectrometry (GC-IRMS)

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