Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies
文献类型：期刊论文
| 作者 | Shi, Gansheng; Mahmood, Asad; Lu, Guanhong; Wang, Xiao; Tong, Shengrui; Ge, Maofa; Xie, Xiaofeng; Sun, Jing |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2019-10-01 |
| 卷号 | 149期号:10页码:2728-2738 |
| ISSN号 | 1011-372X |
| DOI | 10.1007/s10562-019-02813-8 |
| 英文摘要 | In this work, the adsorption and photodegradation of acetaldehyde and ethylene on TiO2 nanoparticles (NPs) with dominant {001} facets were studied. Additionally, the first principle calculation was used to complement the experimental results. TiO2 NPs were synthesized by using a hydrothermal method. The experimental results indicated that adsorption amount of acetaldehyde on TiO2 {001} facets is higher than ethylene, with the initial concentration as 50010ppm. Photodegradation efficiency of 88% was achieved for acetaldehyde in contrast to 17% for ethylene at flow rate of 10sccm. The first principle calculations show that the adsorption energy (E-ads) for acetaldehyde is 0.603eV and that of ethylene is 0.251eV. This study is imperative for understanding the adsorption and photodegradation process of acetaldehyde and ethylene, two typical VOCs, and helpful to design the photocatalysts with high efficiency.[GRAPHICS]. |
| 语种 | 英语 |
| WOS记录号 | WOS:000483692400008 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82584]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Gansheng,Mahmood, Asad,Lu, Guanhong,et al. Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies[J]. CATALYSIS LETTERS,2019,149(10):2728-2738. |
| APA | Shi, Gansheng.,Mahmood, Asad.,Lu, Guanhong.,Wang, Xiao.,Tong, Shengrui.,...&Sun, Jing.(2019).Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies.CATALYSIS LETTERS,149(10),2728-2738. |
| MLA | Shi, Gansheng,et al."Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies".CATALYSIS LETTERS 149.10(2019):2728-2738. |
入库方式： OAI收割
来源：化学研究所
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