Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine
文献类型：期刊论文
| 作者 | Shi, Jinbiao; Zhang, Jianling; Liang, Tongling; Tan, Dongxing; Tan, Xiuniang; Wan, Qiang; Cheng, Xiuyan; Zhang, Bingxing; Han, Buxing; Liu, Lifei |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2019-08-28 |
| 卷号 | 11期号:34页码:30953-30958 |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.9b09879 |
| 英文摘要 | Metal-organic frameworks (MOFs) have attracted increased research attention in photocatalysis due to their great potential in light harvest and conversion. However, the organic transformations as photocatalyzed by MOFs under mild conditions yet remain a challenge. Herein, three bipyridylcontaining cadmium-organic frameworks Cd(dcbpy) (dcbpy = 2,2'-bipyridine-5,5'-dicarboxylate), Cd(bdc)(bpy) (bdc = 1,4-benzenedicarboxylate; bpy = 2,2'-bipyridyl), and Cd(bdc)(2Me-bpy) (2Me-bpy = 4,4'-dimethyl-2,2'-bipyridyl) were synthesized for the first time. The bpy-containing Cd-MOFs have strong light harvest abilities and suitable photocatalysis energy potentials, making them highly active and selective for the photo-oxidation of benzylamine to N-benzylbenzaldimine under mild conditions, i.e., using atmospheric air as oxidant, at room temperature, and in the absence of any photosensitizer or cocatalyst. It provides an efficient, economical, and green way for the direct oxidation of amines to produce imines. |
| 语种 | 英语 |
| WOS记录号 | WOS:000484073400048 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82627]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Jinbiao,Zhang, Jianling,Liang, Tongling,et al. Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(34):30953-30958. |
| APA | Shi, Jinbiao.,Zhang, Jianling.,Liang, Tongling.,Tan, Dongxing.,Tan, Xiuniang.,...&Chen, Gang.(2019).Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine.ACS APPLIED MATERIALS & INTERFACES,11(34),30953-30958. |
| MLA | Shi, Jinbiao,et al."Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine".ACS APPLIED MATERIALS & INTERFACES 11.34(2019):30953-30958. |
入库方式： OAI收割
来源：化学研究所
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