Water inversed helicity of nanostructures from ionic self-assembly of a chiral gelator and an achiral component
文献类型：期刊论文
| 作者 | Liu, Changxia; Yang, Dong; Zhang, Li; Liu, Minghua |
| 刊名 | SOFT MATTER
 |
| 出版日期 | 2019-08-28 |
| 卷号 | 15期号:32页码:6557-6563 |
| ISSN号 | 1744-683X |
| DOI | 10.1039/c9sm01176e |
| 英文摘要 | The ionic self-assemblies (ISAs) formed by a cationic chiral organogelator (l-glutamide amphiphile, abbreviated as PULG) and anionic dyes exhibited helical nanostructures. And the formed helical structures can be tuned by water amount in the ethanol/water solvent. In pure ethanol, the chirality of the gelator was successfully transferred to the achiral components, which was confirmed by the appearance of an induced CD signal in the achiral components. Meanwhile, the electrostatic interaction between the gelator and achiral dyes contributed to the chirality amplification, causing the nanofibrous structures of the gelator to be transformed to uniform left-handed helices. Upon adding water to ethanol, the induced CD signal exhibited inversion from positive to negative. Interestingly, the left-handed helices formed by ISA of PULG/anionic dyes in ethanol were inverted to right-handed helices with the addition of water. Based on detailed investigations of the XRD patterns, CD and UV/Vis spectra, the mechanism of helicity inversion was proposed: left-handed helices were dominated by hydrogen bonding and right-handed helices were dominated by pi-pi stacking. This work exemplifies a feasible method to invert the helicity of chiral nanostructures in co-assembly and gives an insight into the conformation change of biomacromolecules in a biological system. |
| 语种 | 英语 |
| WOS记录号 | WOS:000481424100010 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82633]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Changxia,Yang, Dong,Zhang, Li,et al. Water inversed helicity of nanostructures from ionic self-assembly of a chiral gelator and an achiral component[J]. SOFT MATTER,2019,15(32):6557-6563. |
| APA | Liu, Changxia,Yang, Dong,Zhang, Li,&Liu, Minghua.(2019).Water inversed helicity of nanostructures from ionic self-assembly of a chiral gelator and an achiral component.SOFT MATTER,15(32),6557-6563. |
| MLA | Liu, Changxia,et al."Water inversed helicity of nanostructures from ionic self-assembly of a chiral gelator and an achiral component".SOFT MATTER 15.32(2019):6557-6563. |
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来源：化学研究所
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