Chiral nanostructures self-assembled from nitrocinnamic amide amphiphiles: substituent and solvent effects
文献类型：期刊论文
| 作者 | Jiang, Hejin; Fan, Huahua; Jiang, Yuqian; Zhang, Li; Liu, Minghua |
| 刊名 | BEILSTEIN JOURNAL OF NANOTECHNOLOGY
 |
| 出版日期 | 2019-08-05 |
| 卷号 | 10页码:1608-1617 |
| ISSN号 | 2190-4286 |
| DOI | 10.3762/bjnano.10.156 |
| 英文摘要 | Chiral nanostructures, such as alpha-helical proteins and double helix DNA, are widely found in biological systems and play a significant role in the biofunction of life. These structures are essentially fabricated through the covalent or noncovalent bonds between small chiral molecules. It is thus an important issue to understand how small chiral molecules can form chiral nanostructures. Here, using a series of isomeric nitrocinnamic amide derivatives, we have investigated the self-assembly behavior and the effect of the substituent position as well as the solvent on the formation of chiral nanostructures. It was found that totally different chiral nanostructures were formed due to the different positions of the nitro group on the cinnamic amide. Moreover, it was found that the chiral sense of the self-assembled nanostructures can be regulated by the solvent whereby helicity inversion was observed. This work provides a simple way to regulate the self-assembly pathway via molecular design and choice of solvent for the controlled creation of chiral nanostructures. |
| 语种 | 英语 |
| WOS记录号 | WOS:000479270900001 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82684]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Hejin,Fan, Huahua,Jiang, Yuqian,et al. Chiral nanostructures self-assembled from nitrocinnamic amide amphiphiles: substituent and solvent effects[J]. BEILSTEIN JOURNAL OF NANOTECHNOLOGY,2019,10:1608-1617. |
| APA | Jiang, Hejin,Fan, Huahua,Jiang, Yuqian,Zhang, Li,&Liu, Minghua.(2019).Chiral nanostructures self-assembled from nitrocinnamic amide amphiphiles: substituent and solvent effects.BEILSTEIN JOURNAL OF NANOTECHNOLOGY,10,1608-1617. |
| MLA | Jiang, Hejin,et al."Chiral nanostructures self-assembled from nitrocinnamic amide amphiphiles: substituent and solvent effects".BEILSTEIN JOURNAL OF NANOTECHNOLOGY 10(2019):1608-1617. |
入库方式： OAI收割
来源：化学研究所
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