Ice as Solid Electrolyte to Conduct Various Kinds of Ions
文献类型：期刊论文
| 作者 | Guo, Zeliang; Wang, Tianshuai; Wei, Hehe; Long, Yuanzheng; Yang, Cheng; Wang, Dong; Lang, Jialiang; Huang, Kai; Hussain, Naveed; Song, Chenxi |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2019-09-02 |
| 卷号 | 58期号:36页码:12569-12573 |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201907832 |
| 英文摘要 | Water, considered as a universal solvent to dissolve salts, has been extensively studied as liquid electrolyte in electrochemical devices. The water/ice phase transition at around 0 degrees C presents a common phenomenon in nature, however, the chemical and electrochemical behaviors of ice have rarely been studied. Herein, we discovered that the ice phase provides efficient ionic transport channels and therefore can be applied as generalized solid-state ionic conductor. Solid state ionic conducting ices (ICIs) of Li+, Na+, Mg2+, Al3+, K+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, and Zn2+, frozen from corresponding sulphate solutions, exhibit ionic conductivities ranging from approximate to 10(-7) S cm(-1) (Zn2+) to approximate to 10(-3) S cm(-1) (Li+) at temperatures spanning from -20 degrees C to -5 degrees C. The discovery of ICIs opens new insight to design and fabrication of solid-state electrolytes that are simple, inexpensive, and versatile. |
| 语种 | 英语 |
| WOS记录号 | WOS:000479872100001 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82687]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Zeliang,Wang, Tianshuai,Wei, Hehe,et al. Ice as Solid Electrolyte to Conduct Various Kinds of Ions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(36):12569-12573. |
| APA | Guo, Zeliang.,Wang, Tianshuai.,Wei, Hehe.,Long, Yuanzheng.,Yang, Cheng.,...&Wu, Hui.(2019).Ice as Solid Electrolyte to Conduct Various Kinds of Ions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(36),12569-12573. |
| MLA | Guo, Zeliang,et al."Ice as Solid Electrolyte to Conduct Various Kinds of Ions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.36(2019):12569-12573. |
入库方式： OAI收割
来源：化学研究所
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