Symmetry Breaking in Self-Assembled Nanoassemblies
文献类型：期刊论文
| 作者 | Sang, Yutao; Liu, Minghua |
| 刊名 | SYMMETRY-BASEL
 |
| 出版日期 | 2019-08-01 |
| 卷号 | 11期号:8 |
| DOI | 10.3390/sym11080950 |
| 英文摘要 | The origin of biological homochirality, e.g., life selects the L-amino acids and D-sugar as molecular component, still remains a big mystery. It is suggested that mirror symmetry breaking plays an important role. Recent researches show that symmetry breaking can also occur at a supramolecular level, where the non-covalent bond was crucial. In these systems, equal or unequal amount of the enantiomeric nanoassemblies could be formed from achiral molecules. In this paper, we presented a brief overview regarding the symmetry breaking from dispersed system to gels, solids, and at interfaces. Then we discuss the rational manipulation of supramolecular chirality on how to induce and control the homochirality in the self-assembly system. Those physical control methods, such as Viedma ripening, hydrodynamic macro- and micro-vortex, superchiral light, and the combination of these technologies, are specifically discussed. It is hoped that the symmetry breaking at a supramolecular level could provide useful insights into the understanding of natural homochirality and further designing as well as controlling of functional chiral materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000483559300007 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82692]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sang, Yutao,Liu, Minghua. Symmetry Breaking in Self-Assembled Nanoassemblies[J]. SYMMETRY-BASEL,2019,11(8). |
| APA | Sang, Yutao,&Liu, Minghua.(2019).Symmetry Breaking in Self-Assembled Nanoassemblies.SYMMETRY-BASEL,11(8). |
| MLA | Sang, Yutao,et al."Symmetry Breaking in Self-Assembled Nanoassemblies".SYMMETRY-BASEL 11.8(2019). |
入库方式： OAI收割
来源：化学研究所
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