Boosting the circularly polarized luminescence of small organic molecules via multi-dimensional morphology control
文献类型：期刊论文
| 作者 | Ma, Kai; Chen, Wenjie; Jiao, Tifeng; Jin, Xue; Sang, Yutao; Yang, Dong; Zhou, Jin; Liu, Minghua; Duan, Pengfei |
| 刊名 | CHEMICAL SCIENCE
 |
| 出版日期 | 2019-07-28 |
| 卷号 | 10期号:28页码:6821-6827 |
| ISSN号 | 2041-6520 |
| DOI | 10.1039/c9sc01577a |
| 英文摘要 | Achieving a higher dissymmetry factor is a crucial issue in developing circularly polarized luminescence (CPL) materials. Here, by tailoring the solvent composition and the morphology of the same chiral emissive small molecules (R- or S-SPAn), circularly polarized emission with a boosted dissymmetry factor (two orders) was realized. It was found that by regulating the water fraction in the mixed THF/H2O, we were able to achieve kinetic control over association of chiral emissive R- or S-SPAn into various nanostructures with 0D nanospheres, 2D nanoflakes and 3D stacked nanoflakes. These nanostructures are all CPL active. Remarkably, the dissymmetry factors of the nanostructures were significantly enhanced compared to those of the molecules and further boosted in different morphologies, from similar to 10(-4) (0D nanospheres) to 10(-3) (2D flake) to similar to 10(-2) (3D nanoflakes). The enlarged g(lum) value could be assigned to a good packing induced strong luminescence of an excimer. This strategy provides an efficient way to fabricate higher dissymmetry factor CPL organic nanomaterials by only changing the supramolecular architectures while using the same chiral small molecules. |
| 语种 | 英语 |
| WOS记录号 | WOS:000476545100005 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82720]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Kai,Chen, Wenjie,Jiao, Tifeng,et al. Boosting the circularly polarized luminescence of small organic molecules via multi-dimensional morphology control[J]. CHEMICAL SCIENCE,2019,10(28):6821-6827. |
| APA | Ma, Kai.,Chen, Wenjie.,Jiao, Tifeng.,Jin, Xue.,Sang, Yutao.,...&Duan, Pengfei.(2019).Boosting the circularly polarized luminescence of small organic molecules via multi-dimensional morphology control.CHEMICAL SCIENCE,10(28),6821-6827. |
| MLA | Ma, Kai,et al."Boosting the circularly polarized luminescence of small organic molecules via multi-dimensional morphology control".CHEMICAL SCIENCE 10.28(2019):6821-6827. |
入库方式： OAI收割
来源：化学研究所
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