Integrated polyamide thin-film nanofibrous composite membrane regulated by functionalized interlayer for efficient water/isopropanol separation
文献类型：期刊论文
| 作者 | Cao XZ(曹兴忠) ; Hsiao, BS; Wang, XF; Wang, BY; Cao, XZ; Zhang, TH; Shen, K; Li, PY; Cheng, C; Wang BY(王宝义)
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| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2018 |
| 卷号 | 553页码:70-81 |
| 关键词 | Modified graphene oxide interlayer Thin-film nanofibrous composite membrane Interfacial polymerization Pervaporation |
| ISSN号 | 0376-7388 |
| DOI | 10.1016/j.memsci.2018.02.013 |
| 文献子类 | Article |
| 英文摘要 | A novel polyamide thin film nanofibrous composite (TFNC) membrane was fabricated by interfacial polymerization (IP) with a modified graphene oxide interlayer on highly porous electrospun polyacrylonitrile (PAN) nanofibrous substrate for isopropanol dehydration by pervaporation. Benefiting from the utilization of ethylenediamine modified graphene oxide (eGO) lamellae, which provided thin and relatively smooth surface but also reaction sites (amine groups) for interfacial polymerization, the resultant TFNC membranes exhibited an integrated structure with a compacter and thinner polyamide (PA) selective skin layer. Significantly, the skillful regulation of interfacial polymerization by the control of deposition amount of eGO on nanofibrous substrate enabled the strong interfacial interaction and the formation of compact selective layer, determining the augment of selectivity of TFNC membranes. The optimized PA/eGO/PAN integrated TFNC membranes exhibited an excellent separation performance for dehydrating 90 wt% aqueous isopropanol solution with remarkably enhanced separation factor (1866) and high permeate flux (4150 g/m(2) h) at 70 degrees C. This result was markedly superior to those of TFC membranes prepared by IP reported so far, suggesting an efficient and facile approach to fabricate high performance pervaporation membrane with unique structures. |
| 电子版国际标准刊号 | 1873-3123 |
| WOS关键词 | GRAPHENE-OXIDE ; INTERFACIAL POLYMERIZATION ; NANOFILTRATION MEMBRANE ; PERVAPORATION SEPARATION ; ISOPROPANOL DEHYDRATION ; ETHANOL DEHYDRATION ; WATER-TRANSPORT ; HIGH-FLUX ; PERFORMANCE ; DESALINATION |
| WOS研究方向 | Engineering ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000428131700009 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285749]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Cao XZ,Hsiao, BS,Wang, XF,et al. Integrated polyamide thin-film nanofibrous composite membrane regulated by functionalized interlayer for efficient water/isopropanol separation[J]. JOURNAL OF MEMBRANE SCIENCE,2018,553:70-81. |
| APA | 曹兴忠.,Hsiao, BS.,Wang, XF.,Wang, BY.,Cao, XZ.,...&王宝义.(2018).Integrated polyamide thin-film nanofibrous composite membrane regulated by functionalized interlayer for efficient water/isopropanol separation.JOURNAL OF MEMBRANE SCIENCE,553,70-81. |
| MLA | 曹兴忠,et al."Integrated polyamide thin-film nanofibrous composite membrane regulated by functionalized interlayer for efficient water/isopropanol separation".JOURNAL OF MEMBRANE SCIENCE 553(2018):70-81. |
入库方式： OAI收割
来源：高能物理研究所
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