Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts
文献类型：期刊论文
| 作者 | Rong, HP; Xin, PY; Li, J; Xiong, Y; Wu, X; Dong, JC ; Chen, WX; Wang, Y; Gu, L; Luo, J
|
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:17页码:4642-4646 |
| 关键词 | aerobic oxidation benzyl alcohol palladium clusters single atom catalysts supported catalysts |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201801103 |
| 文献子类 | Article |
| 英文摘要 | The active species in supported metal catalysts are elusive to identify, and large quantities of inert species can cause significant waste. Herein, using a stoichiometrically precise synthetic method, we prepare atomically dispersed palladium-cerium oxide (Pd-1/CeO2) and hexapalladium cluster-cerium oxide (Pd-6/CeO2), as confirmed by spherical-aberration-corrected transmission electron microscopy and X-ray absorption fine structure spectroscopy. For aerobic alcohol oxidation, Pd-1/CeO2 shows extremely high catalytic activity with a TOF of 6739 h(-1) and satisfactory selectivity (almost 100% for benzaldehyde), while Pd-6/CeO2 is inactive, indicating that the true active species are single Pd atoms. Theoretical simulations reveal that the bulkier Pd-6 clusters hinder the interactions between hydroxy groups and the CeO2 surface, thus suppressing synergy of Pd-Ce perimeter. |
| 电子版国际标准刊号 | 1521-3773 |
| WOS关键词 | SINGLE-ATOM ; METAL NANOPARTICLES ; BENZYL ALCOHOL ; GOLD ; PD ; HYDROGENATION ; DEHYDRATION ; REACTIVITY ; MECHANISM ; GRAPHENE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000430165700034 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285830]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Rong, HP,Xin, PY,Li, J,et al. Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(17):4642-4646. |
| APA | Rong, HP.,Xin, PY.,Li, J.,Xiong, Y.,Wu, X.,...&Chen, C.(2018).Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(17),4642-4646. |
| MLA | Rong, HP,et al."Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.17(2018):4642-4646. |
入库方式： OAI收割
来源：高能物理研究所
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