Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties
文献类型：期刊论文
| 作者 | Zhao R(赵然) ; Mei L(梅雷); Hu KQ(胡孔球); Tian M(田明); Chai ZF(柴之芳); Shi WQ(石伟群); Zhao, R; Mei, L; Hu, KQ; Tian, M
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| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:10页码:6084-6094 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.incagchem.8h00634 |
| 文献子类 | Article |
| 英文摘要 | A bifunctional ligand, 2,2'-bipyridine-4,4'-dicarboxylic acid (H(2)bpdc), has been used in the investigation of constructing bimetallic uranyl organic frameworks (UOFs). Seven novel uranyl transition metal bimetallic coordination polymers, [(UO2)Zn(bpdc)(2)](n) (1), [Cd(UO2)(bpdc)(2)(H2O)(2.) 2H(2)O](n) (2), [Cu(UO2)(bpdc)(SO4)(H2O)(3.)2H(2)O](n) (3), [CuCl-(UO2) (bpdc) (Hbpdc) (H2O)(2.)H2O](n) (4), [Cu(UO2)-(bpdc)(2)(H2O)](n) (5), [Co-2(UO2)(3)(bpdc)(6)](n) (6), and [Co-3(UO2)(4)(bpdc)(8)(Hbpdc)(H2O)(2)]n (7), have been successfully constructed through the assembly of various transition-metal salts, uranyl ions, and H(2)bpdc ligands under hydrothermal conditions. UOFs 1, 5, 6, and 7 adopt three-dimensional (3D) frameworks with different architectures; UOFs 2 and 3 exhibit two-dimensional (2D) wavelike and stairlike layers, respectively, while UOF 4 is a one-dimensional (1D) chain assembly. These UOFs include a wide range of dimensionalities (ID-3D), interpenetrated frameworks, and cation cation interaction species, suggesting that anion-dependent structure regulation based on the metalloligand [M(bpdc)(m)](n)-motifs, the coordination modes of the metal centers and bpdc(2)-ligands, along with the reaction temperature, has a remarkable influence on the formation of bimetallic UOFs, which could be a representative system for the structural modulation of UOFs with various dimensionalities and structures. Furthermore, the thermal stability and luminescent properties of compounds 1, 3, and 6 are also investigated. |
| 电子版国际标准刊号 | 1520-510X |
| WOS关键词 | SELECTIVE DYE ADSORPTION ; COORDINATION POLYMERS ; HETEROMETALLIC COMPLEXES ; AQUEOUS-SOLUTIONS ; HYBRID MATERIALS ; ACID ; TOPOLOGY ; 4,4-DICARBOXY-2,2-BIPYRIDINE ; FLUORESCENCE ; DEHYDRATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000433013600040 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285947]  |
| 专题 | 高能物理研究所_多学科研究中心 中国科学院高能物理研究所_中国散裂中子源 |
| 通讯作者 | Shi WQ(石伟群) |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhao R,Mei L,Hu KQ,et al. Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties[J]. INORGANIC CHEMISTRY,2018,57(10):6084-6094. |
| APA | 赵然.,梅雷.,胡孔球.,田明.,柴之芳.,...&Shi, WQ.(2018).Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties.INORGANIC CHEMISTRY,57(10),6084-6094. |
| MLA | 赵然,et al."Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties".INORGANIC CHEMISTRY 57.10(2018):6084-6094. |
入库方式： OAI收割
来源：高能物理研究所
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