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Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution
文献类型：期刊论文
| 作者 | Luo, ZY; Ouyang, YX; Zhang, H ; Xiao, ML; Ge, JJ; Jiang, Z; Wang, JL; Tang, DM; Cao, XZ; Liu, CP
|
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2018 |
| 卷号 | 9页码:2120 |
| ISSN号 | 2041-1723 |
| DOI | 10.1038/s41467-018-04501-4 |
| 文献子类 | Article |
| 英文摘要 | Lacking strategies to simultaneously address the intrinsic activity, site density, electrical transport, and stability problems of chalcogels is restricting their application in catalytic hydrogen production. Herein, we resolve these challenges concurrently through chemically activating the molybdenum disulfide (MoS2) surface basal plane by doping with a low content of atomic palladium using a spontaneous interfacial redox technique. Palladium substitution occurs at the molybdenum site, simultaneously introducing sulfur vacancy and converting the 2H into the stabilized 1T structure. Theoretical calculations demonstrate the sulfur atoms next to the palladium sites exhibit low hydrogen adsorption energy at -0.02 eV. The final MoS2 doped with only 1wt% of palladium demonstrates exchange current density of 805 mu A cm(-2) and 78 mV overpotential at 10 mA cm(-2), accompanied by a good stability. The combined advantages of our surface activating technique open the possibility of manipulating the catalytic performance of MoS2 to rival platinum. |
| WOS关键词 | INITIO MOLECULAR-DYNAMICS ; GENERALIZED GRADIENT APPROXIMATION ; ACTIVE EDGE SITES ; MOLYBDENUM-DISULFIDE ; SULFUR VACANCIES ; LIQUID-METALS ; NANOSHEETS ; MONOLAYER ; CATALYST ; PHASE |
| WOS研究方向 | Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000433299000003 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285967]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Luo, ZY,Ouyang, YX,Zhang, H,et al. Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution[J]. NATURE COMMUNICATIONS,2018,9:2120. |
| APA | Luo, ZY.,Ouyang, YX.,Zhang, H.,Xiao, ML.,Ge, JJ.,...&曹兴忠.(2018).Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution.NATURE COMMUNICATIONS,9,2120. |
| MLA | Luo, ZY,et al."Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution".NATURE COMMUNICATIONS 9(2018):2120. |
入库方式： OAI收割
来源：高能物理研究所
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