Ultrasensitive detection of thiophenol based on a water-soluble pyrenyl probe
文献类型：期刊论文
| 作者 | Yao ZY(姚志轶) ; Yao, ZY; Ge, WQ; Guo, MW; Xiao, KR; Qiao, YD; Cao, Z; Wu, HC; Qiao YD(乔亚东)
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| 刊名 | TALANTA
 |
| 出版日期 | 2018 |
| 卷号 | 185页码:146-150 |
| 关键词 | Pyrene Fluorescent probe Thiophenol Water-soluble Bioimaging |
| ISSN号 | 0039-9140 |
| DOI | 10.1016/j.talanta.2018.03.068 |
| 文献子类 | Article |
| 英文摘要 | We report a simple pyrene-based fluorescent probe, sodium 8-(2,4-dinitrophenoxy)pyrene-1,3,6-trisulfonate (HPTS-DNP), for the ultrasensitive and visual detection of thiophenol in 100% aqueous media. The sensing mechanism of this method is based on nucleophilic aromatic substitution on HPTS-DNP caused by thiophenol to afford a highly fluorescent product, 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt (HPTS). The extremely low fluorescence background of HPTS-DNP and high quantum yield of HPTS ensure the superior sensing performance toward thiophenol, including rapid responses, off-on detection mode and excellent sensitivity. The detection limit is as low as 0.49 nmol L-1 according to the measurements with a spectrofluorimeter. This probe also features good selectivity (response ratio of thiophenol to interferents > 30), precision (2.93%) and accuracy (102%). This approach could be applied for monitoring the thiophenol concentrations in environmental water samples. HPTS-DNP also showed good cell permeation capacity and low cellular cytotoxicity, indicating further application in bioimaging studies. |
| 电子版国际标准刊号 | 1873-3573 |
| WOS关键词 | SELECTIVE FLUORESCENT-PROBE ; LIVING CELLS ; SENSITIVE DETECTION ; SAMPLES ; THIOLS ; PH ; TOXICITY ; EMISSION ; SULFIDES ; PYRANINE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000433656200020 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285973]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 通讯作者 | Yao ZY(姚志轶) |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Yao ZY,Yao, ZY,Ge, WQ,et al. Ultrasensitive detection of thiophenol based on a water-soluble pyrenyl probe[J]. TALANTA,2018,185:146-150. |
| APA | 姚志轶.,Yao, ZY.,Ge, WQ.,Guo, MW.,Xiao, KR.,...&乔亚东.(2018).Ultrasensitive detection of thiophenol based on a water-soluble pyrenyl probe.TALANTA,185,146-150. |
| MLA | 姚志轶,et al."Ultrasensitive detection of thiophenol based on a water-soluble pyrenyl probe".TALANTA 185(2018):146-150. |
入库方式： OAI收割
来源：高能物理研究所
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