Cobalt Covalent Doping in MoS2 to Induce Bifunctionality of Overall Water Splitting
文献类型：期刊论文
| 作者 | Liu, PF ; Zheng, LR; Wang, GZ; Yang, HG; Wong, PK; Zhang, HM; Zhao, HJ; Zheng LR(郑黎荣); Wang, Y; Xiong, QZ
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| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2018 |
| 卷号 | 30期号:29页码:1801450 |
| 关键词 | bifunctional electrocatalysts cobalt covalent doping MoS2 overall water splitting vapor-phase hydrothermal method |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.201801450 |
| 文献子类 | Article |
| 英文摘要 | The layer-structured MoS2 is a typical hydrogen evolution reaction (HER) electrocatalyst but it possesses poor activity for the oxygen evolution reaction (OER). In this work, a cobalt covalent doping approach capable of inducing HER and OER bifunctionality into MoS2 for efficient overall water splitting is reported. The results demonstrate that covalently doping cobalt into MoS2 can lead to dramatically enhanced HER activity while simultaneously inducing remarkable OER activity. The catalyst with optimal cobalt doping density can readily achieve HER and OER onset potentials of -0.02 and 1.45 V (vs reversible hydrogen electrode (RHE)) in 1.0 m KOH. Importantly, it can deliver high current densities of 10, 100, and 200 mA cm(-2) at low HER and OER overpotentials of 48, 132, 165 mV and 260, 350, 390 mV, respectively. The reported catalyst activation approach can be adapted for bifunctionalization of other transition metal dichalcogenides. |
| 电子版国际标准刊号 | 1521-4095 |
| WOS关键词 | ELECTROCATALYTIC HYDROGEN EVOLUTION ; LITHIUM-ION BATTERIES ; MOLYBDENUM-CARBIDE ; ULTRATHIN NANOSHEETS ; PHASE-TRANSFORMATION ; NEUTRAL CONDITIONS ; NICKEL FOAM ; EFFICIENT ; CATALYSTS ; OXYGEN |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000438709400027 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/286118]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Liu, PF,Zheng, LR,Wang, GZ,et al. Cobalt Covalent Doping in MoS2 to Induce Bifunctionality of Overall Water Splitting[J]. ADVANCED MATERIALS,2018,30(29):1801450. |
| APA | Liu, PF.,Zheng, LR.,Wang, GZ.,Yang, HG.,Wong, PK.,...&Xiong, QZ.(2018).Cobalt Covalent Doping in MoS2 to Induce Bifunctionality of Overall Water Splitting.ADVANCED MATERIALS,30(29),1801450. |
| MLA | Liu, PF,et al."Cobalt Covalent Doping in MoS2 to Induce Bifunctionality of Overall Water Splitting".ADVANCED MATERIALS 30.29(2018):1801450. |
入库方式： OAI收割
来源：高能物理研究所
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