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New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel

文献类型：期刊论文

作者Zhang, ML; Wang, P; Zhang, YM; Ji, DB; Yan, YD; Shi, WQ; Huang, Q; Du, SY; Shi WQ(石伟群)
刊名ELECTROCHEMISTRY COMMUNICATIONS
出版日期2018
卷号93页码:180-182
关键词Bimodal effect Reduction potential Atomic radius difference Electronegativity difference Hume-Rothery's rules
ISSN号1388-2481
DOI10.1016/j.elecom.2018.07.013
文献子类Article
英文摘要In this work, the electrochemical behavior of lanthanides (except promethium) on several active cathodes in LiCl-KCl molten salts was investigated. We have discovered that the reduction potentials of lanthanide alloys present a "bimodal effect". A numerical model was established based on the result of multiple linear regression analyses, which indicates that the reduction potentials are correlated with differences in atomic radii and differences in electronegativity. Employing the fitted formulae, which provide a preliminary model of the behavior of these elements in electrolysis-based pyroprocessing, the electrochemistry of both lanthanides and actinides on active metal cathodes could be reasonably estimated.
电子版国际标准刊号1873-1902
WOS关键词MOLTEN-SALT ; ELECTRONEGATIVITY ; ELECTRODES ; ENERGY
WOS研究方向Electrochemistry
语种英语
WOS记录号WOS:000439858800039
源URL[http://ir.ihep.ac.cn/handle/311005/286151]  
专题高能物理研究所_核技术应用研究中心
高能物理研究所_多学科研究中心
通讯作者Shi WQ(石伟群)
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714		 Zhang, ML,Wang, P,Zhang, YM,et al. New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel[J]. ELECTROCHEMISTRY COMMUNICATIONS,2018,93:180-182.
APA Zhang, ML.,Wang, P.,Zhang, YM.,Ji, DB.,Yan, YD.,...&石伟群.(2018).New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel.ELECTROCHEMISTRY COMMUNICATIONS,93,180-182.
MLA Zhang, ML,et al."New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel".ELECTROCHEMISTRY COMMUNICATIONS 93(2018):180-182.

入库方式： OAI收割

来源：高能物理研究所

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