Polydopamine-enabled distribution of polysiloxane domains in polyamide thin-film nanocomposite membranes for organic solvent nanofiltration
文献类型：期刊论文
| 作者 | Cao, XZ ; Lu EY(卢二阳); 张鹏(正); Cao XZ(曹兴忠); Lu, EY; Mu, WR; Wang, JT; Liu, H; Zhang, P; Qin, YT
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| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2018 |
| 卷号 | 205页码:140-150 |
| 关键词 | Thin-film nanocomposite membrane Polydopamine nanoparticle Poly(dimethylsiloxane) Polyethyleneimine Organic solvent nanofiltration |
| ISSN号 | 1383-5866 |
| DOI | 10.1016/j.seppur.2018.05.034 |
| 文献子类 | Article |
| 英文摘要 | Thin-film nanocomposite (TFN) membranes have attracted growing interests for improving the energy efficiency of many chemical separation processes, while well-designed microstructures are essential to acquire high permeation flux, high selectivity and high stability for different types of permeates. Herein, a novel strategy to regulate the microstructures and solvent permeation properties of TFN membranes is developed. Hydrophobic polysiloxane domains are proposed to be evenly distributed within hydrophilic polyamide matrix with the mediation of polydopamine nanoparticles (PDNPs). To be specific, PDNPs treated by 3-(triethoxysilyl)- propylamine (APTES) allow PDMS converge on its surface, so as to form nano-sized poly(dimethylsiloxane) (PDMS) domains within the active layer of TFN membranes. With polyethyleneimine (PEI) as the aqueous phase monomer during conventional interfacial polymerization (IP), trimesoyl chloride not only acts as the oil phase monomer, but also reacts with the terminal hydroxyl groups of PDMS, facilitating the uniform dispersion of the nanoparticles within the PEI matrix. By tuning the ratio of PDNPs to PDMS, PDMS could be uniformly dispersed within the active layer together with PDNPs, which effectively construct hydrophobic pathways for nonpolar solvents. A maximum permeate flux for n-heptane of 7.9 L m(-2)h(-1) bar(-1) at 10 bar is achieved, along with moderate area swelling (3.16%) and rather low MWCOs (below 400). Meanwhile, these TFN membranes containing PDMS domains still display appropriate permeate fluxes for polar solvents due to the maintenance of hydrophilic pathways, as well as enhanced rejection ability and potential long-term operation stability than the control membranes. |
| 电子版国际标准刊号 | 1873-3794 |
| WOS关键词 | HOLLOW-FIBER MEMBRANES ; FILLED POLYDIMETHYLSILOXANE PDMS ; MIXED MATRIX MEMBRANES ; RESISTANT NANOFILTRATION ; COMPOSITE MEMBRANES ; SURFACE-CHEMISTRY ; SEPARATION ; PERFORMANCE ; FLUX ; PERVAPORATION |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000441650000015 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/286220]  |
| 专题 | 高能物理研究所_多学科研究中心 高能物理研究所_实验物理中心 高能物理研究所_加速器中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Cao, XZ,Lu EY,Zhang P,et al. Polydopamine-enabled distribution of polysiloxane domains in polyamide thin-film nanocomposite membranes for organic solvent nanofiltration[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2018,205:140-150. |
| APA | Cao, XZ.,卢二阳.,张鹏.,曹兴忠.,Lu, EY.,...&Li, YF.(2018).Polydopamine-enabled distribution of polysiloxane domains in polyamide thin-film nanocomposite membranes for organic solvent nanofiltration.SEPARATION AND PURIFICATION TECHNOLOGY,205,140-150. |
| MLA | Cao, XZ,et al."Polydopamine-enabled distribution of polysiloxane domains in polyamide thin-film nanocomposite membranes for organic solvent nanofiltration".SEPARATION AND PURIFICATION TECHNOLOGY 205(2018):140-150. |
入库方式： OAI收割
来源：高能物理研究所
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