An efficient sodium-ion battery consisting of reduced graphene oxide bonded Na3V2(PO4)(3) in a composite carbon network
文献类型：期刊论文
| 作者 | Fang, YY; Zhou, XS; Bao, JC; Zhang, ZZ; Liu, SH; Liu SH(刘树虎) ; Gu, EL
|
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2018 |
| 卷号 | 767页码:131-140 |
| 关键词 | Na3V2(PO4)(3) Reduced graphene oxide Carbon nanotubes Sodium-ion battery Cathode Ex situ X-ray absorption near edge structure spectroscopy |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2018.07.082 |
| 文献子类 | Article |
| 英文摘要 | Sodium-ion batteries have been considered as the most promising candidate for large-scale energy storage applications. However, the poor cycling stability and inferior rate capability of existing cathode materials for sodium-ion batteries restrict future developments. Herein, we report a chemically bonded cathode material for sodium-ion batteries that is synthesized by freeze-drying and subsequent annealing to generate Na3V2(PO4)(3)/reduced graphene oxide-carbon nanotubes (NGC) composite. The NGC composite with 79 wt % Na3V2(PO4)(3) shows a high initial Coulombic efficiency (>93%) and high specific capacity with superior cycling stability (similar to 105 mAh g(-1) after 500 cycles at 1 C based on the mass of Na3V2(PO4)(3)). More importantly, in situ electrochemical impedance spectroscopy and ex situ X-ray diffraction, X-ray photoelectron spectroscopy, X-ray absorption near edge structure spectroscopy, and transmission electronic microscopy are employed to reveal the robust V-O-N bonding and excellent sodium storage performance of the NGC composite. (C) 2018 Elsevier B.V. All rights reserved. |
| 电子版国际标准刊号 | 1873-4669 |
| WOS关键词 | HIGH-PERFORMANCE ANODE ; HIGH-CAPACITY ANODE ; ELECTROCHEMICAL PERFORMANCE ; COATED NA3V2(PO4)(3) ; CYCLING STABILITY ; CATHODE MATERIALS ; SUPERIOR CATHODE ; DOPED CARBON ; STORAGE ; NANOTUBES |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000446316500017 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/286390]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Fang, YY,Zhou, XS,Bao, JC,et al. An efficient sodium-ion battery consisting of reduced graphene oxide bonded Na3V2(PO4)(3) in a composite carbon network[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2018,767:131-140. |
| APA | Fang, YY.,Zhou, XS.,Bao, JC.,Zhang, ZZ.,Liu, SH.,...&Gu, EL.(2018).An efficient sodium-ion battery consisting of reduced graphene oxide bonded Na3V2(PO4)(3) in a composite carbon network.JOURNAL OF ALLOYS AND COMPOUNDS,767,131-140. |
| MLA | Fang, YY,et al."An efficient sodium-ion battery consisting of reduced graphene oxide bonded Na3V2(PO4)(3) in a composite carbon network".JOURNAL OF ALLOYS AND COMPOUNDS 767(2018):131-140. |
入库方式： OAI收割
来源：高能物理研究所
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