电子束辐照降解水体中磺胺间甲氧嘧啶
文献类型:期刊论文
作者 | Zhang, Yang; 张洋; 付兴明; 罗敏; 肖扬; 马玲玲(多); 徐殿斗![]() ![]() |
刊名 | 中国环境科学
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出版日期 | 2018 |
卷号 | 38期号:7页码:2520-2526 |
ISSN号 | 1000-6923 |
其他题名 | Studies on the degradation of sulfamonomethoxine by electron beam irradiation in aqueous solution |
文献子类 | Article |
英文摘要 | The process of removing sulfamonomethoxine (SMM) 10mg/L in aqueous systems was preliminarily explored by electron beam irradiation (EBI). Several factors such as absorbed dose, radical scavenger and inorganic salts affecting on the removal efficiency were examined. Degradation mechanism and pathway were proposed through both experimental data and simulation calculation. The toxicity of degradation products was also evaluated. The removal rate of SMM was 99% at 3.0kGy. The data demonstrated that reduction elimination reaction played the key role. SMM degradation fitted the first-order kinetic equation. The degradation efficiency of SMM was inhibited to a certain extent when there were some inorganic ions (CO32-, SO42-, and NO3-). Nine kinds of possible degradation products and corresponding degradation pathways were deduced from the analysis of the degradation products by ultra-high performance liquid chromatography-mass spectrometry (UHPLC-MS) with the assistance of theoretical calculation results by Gaussian 03 software as well. The toxicity test of Vibrio fernuli showed that the toxicity of the irradiated intermediates increased first and then decreased and reached the maximum at the absorption dose of 2.0kGy © 2018, Editorial Board of China Environmental Science. All right reserved. |
语种 | 中文 |
CSCD记录号 | CSCD:6286094 |
源URL | [http://ir.ihep.ac.cn/handle/311005/286647] ![]() |
专题 | 高能物理研究所_核技术应用研究中心 高能物理研究所_多学科研究中心 |
通讯作者 | 罗敏 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Zhang, Yang,张洋,付兴明,等. 电子束辐照降解水体中磺胺间甲氧嘧啶[J]. 中国环境科学,2018,38(7):2520-2526. |
APA | Zhang, Yang.,张洋.,付兴明.,罗敏.,肖扬.,...&宋浩军.(2018).电子束辐照降解水体中磺胺间甲氧嘧啶.中国环境科学,38(7),2520-2526. |
MLA | Zhang, Yang,et al."电子束辐照降解水体中磺胺间甲氧嘧啶".中国环境科学 38.7(2018):2520-2526. |
入库方式: OAI收割
来源:高能物理研究所
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