Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6)
文献类型：期刊论文
| 作者 | Zheng, Lirong, Chen, Jun; Zheng LR(郑黎荣) ; Xing, Xianran; Gao, Qilong, Shi, Naike, Sanson,; rea, Sun, Yu, Milazzo, Ruggero, Olivi, Luca, Zhu, He, Lapidus, Saul H.
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| 刊名 | INORGANIC CHEMISTRY
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| 出版日期 | 2018 |
| 卷号 | 57期号:22页码:14027-14030 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.8b02428 |
| 文献子类 | Article |
| 英文摘要 | The achievement of controlling thermal expansion is important for open-framework structures. The present work proposes a feasible way to adjust the coefficient of thermal expansion continuously from negative to positive via inserting guest Na+ ions or H2O molecules into a GaFe(CN)(6) framework. The guest ions or molecules have an intense dampening effect on the transverse vibrations of CN atoms in the -Ga-N C- Fe- linkage, especially for the N atoms. This study demonstrates that electrochemical or redox intercalation of guest ions will be an effective way to tune thermal expansion in those negative thermal expansion open framework materials induced by low-frequency phonons. |
| 电子版国际标准刊号 | 1520-510X |
| WOS关键词 | CRYSTAL |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000451244700051 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/286863]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zheng, Lirong, Chen, Jun,Zheng LR,Xing, Xianran,et al. Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6)[J]. INORGANIC CHEMISTRY,2018,57(22):14027-14030. |
| APA | Zheng, Lirong, Chen, Jun,郑黎荣,Xing, Xianran,Gao, Qilong, Shi, Naike, Sanson,,&rea, Sun, Yu, Milazzo, Ruggero, Olivi, Luca, Zhu, He, Lapidus, Saul H..(2018).Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6).INORGANIC CHEMISTRY,57(22),14027-14030. |
| MLA | Zheng, Lirong, Chen, Jun,et al."Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6)".INORGANIC CHEMISTRY 57.22(2018):14027-14030. |
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来源：高能物理研究所
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