Charge Transfer at Hybrid Organic-Inorganic Interface
文献类型:期刊论文
作者 | Rehman, AU; Zhang, HJ; Peng, W; Razaq, A; Ibrahim, K; Bao, SN |
刊名 | ACTA PHYSICA POLONICA A
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出版日期 | 2018 |
卷号 | 134期号:1页码:434-437 |
关键词 | FePc Si (100) Cu(100) STM PES nanostructures work function charge density interface dipole |
ISSN号 | 0587-4246 |
DOI | 10.12693/APhysPolA.134.434 |
文献子类 | Article; Proceedings Paper |
英文摘要 | Iron phthalocyanine molecule (FePc) thin films were deposited on Cu(100) and Si(100) substrates in sequential steps and the interface was characterized by means of scanning tunneling microscope, X-ray photoemission spectroscopy, and its sister technique ultra violet photoemission spectroscopy. At room temperature disordered structures are observed. However at elevated temperature approximate to 480 degrees C, a long range ordered pattern is noticed indicating the increase of diffusion of adsorbed molecules on the substrate surface. All the photoemission spectra exhibited a clear change and shift in the adsorbed peaks. The change in binding energy of C 1 s core level as revealed by X-ray photoemission spectroscopy is V-b = 0:18 eV. Our calculated work function of the clean Si (100) surface is 4.09 eV. The hole and electron injection barriers are estimated as 1.22 eV and -1.38 eV, respectively. Based on the measured quantities, the interface dipole potential is found to be -0.04 eV. A minute charge transferred from each adsorbed molecule to the substrate is estimated as ca: 8.565 x 10(-22) C. Besides, our computational density functional theory findings revealed a strong adsorbate-substrate interaction. |
会议地点 | Fethiye, TURKEY |
电子版国际标准刊号 | 1898-794X |
WOS关键词 | SCANNING-TUNNELING-MICROSCOPY ; METAL PHTHALOCYANINES ; ELECTRONIC-STRUCTURE ; CO |
WOS研究方向 | Physics |
语种 | 英语 |
WOS记录号 | WOS:000451281600114 |
源URL | [http://ir.ihep.ac.cn/handle/311005/286975] ![]() |
专题 | 高能物理研究所_多学科研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Rehman, AU,Zhang, HJ,Peng, W,et al. Charge Transfer at Hybrid Organic-Inorganic Interface[J]. ACTA PHYSICA POLONICA A,2018,134(1):434-437. |
APA | Rehman, AU,Zhang, HJ,Peng, W,Razaq, A,Ibrahim, K,&Bao, SN.(2018).Charge Transfer at Hybrid Organic-Inorganic Interface.ACTA PHYSICA POLONICA A,134(1),434-437. |
MLA | Rehman, AU,et al."Charge Transfer at Hybrid Organic-Inorganic Interface".ACTA PHYSICA POLONICA A 134.1(2018):434-437. |
入库方式: OAI收割
来源:高能物理研究所
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