Efficient low-temperature hydrogenation of acetone on bimetallic Pt-Ru/C catalyst
文献类型：期刊论文
| 作者 | Yang, Z1; Chen, WH; Zheng, JB; Yang, ZQ; Zhang, NW; Zhong, CJ; Chen, BH |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2018-07-01 |
| 卷号 | 363页码:52-62 |
| 关键词 | Annealing treatment C=O hydrogenation Synergetic behavior Structure-function relationship |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2018.04.011 |
| 英文摘要 | Carbon supported Pt-Ru nano-alloy with multiple reactive sites exhibits unprecedentedly efficient performance in acetone hydrogenation at room temperature. Catalytic properties can be controllably regulated and optimized via performing the specific annealing treatment for the catalyst. The essential correlation between the variations in catalyst's annealing conditions and the resultant variation in catalytic properties has been explored and discussed as a structure-function relationship. The combination of Pt and Ru sites exhibits enhanced catalytic activity compared with monometallic ones. Larger PtRu alloy particle size favors the rapid C=O hydrogenation and the improvement of catalytic selectivity to isopropanol. Isopropyl ether generation is related to the Pt defect sites on the surface, which can be blocked though the catalyst's oxidation treatment. The presence of surface metal-oxide species is beneficial to the performance enhancement, resulting from the synergetic behavior between metal-oxide sites and metallic sites on respectively activating the reactants. Moreover, 3-pentanone is used as a probe molecule to verify the structure-function relationship of catalytic low-temperature C=O hydrogenation on PtRu/C. (C) 2018 Elsevier Inc. All rights reserved. |
| 学科主题 | Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000437365200006 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/80122]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 1.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem & Biochem Engn, Natl Engn Lab Green Prod Alcohols Ethers Esters, Xiamen 361005, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.SUNY Binghamton, Dept Chem, Binghamton, NY USA |
| 推荐引用方式 GB/T 7714 | Yang, Z,Chen, WH,Zheng, JB,et al. Efficient low-temperature hydrogenation of acetone on bimetallic Pt-Ru/C catalyst[J]. JOURNAL OF CATALYSIS,2018,363:52-62. |
| APA | Yang, Z.,Chen, WH.,Zheng, JB.,Yang, ZQ.,Zhang, NW.,...&Chen, BH.(2018).Efficient low-temperature hydrogenation of acetone on bimetallic Pt-Ru/C catalyst.JOURNAL OF CATALYSIS,363,52-62. |
| MLA | Yang, Z,et al."Efficient low-temperature hydrogenation of acetone on bimetallic Pt-Ru/C catalyst".JOURNAL OF CATALYSIS 363(2018):52-62. |
入库方式： OAI收割
来源：金属研究所
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