Unmasking chloride attack on the passive film of metals
文献类型：期刊论文
| 作者 | Zhang, B; Wang, J; Wu, B; Guo, XW; Wang, YJ; Chen, D; Zhang, YC; Du, K; Oguzie, EE; Ma, XL |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2018-07-02 |
| 卷号 | 9页码:- |
| ISSN号 | 2041-1723 |
| DOI | 10.1038/s41467-018-04942-x |
| 英文摘要 | Nanometer-thick passive films on metals usually impart remarkable resistance to general corrosion but are susceptible to localized attack in certain aggressive media, leading to material failure with pronounced adverse economic and safety consequences. Over the past decades, several classic theories have been proposed and accepted, based on hypotheses and theoretical models, and oftentimes, not sufficiently nor directly corroborated by experimental evidence. Here we show experimental results on the structure of the passive film formed on a FeCr15Ni15 single crystal in chloride-free and chloride-containing media. We use aberration-corrected transmission electron microscopy to directly capture the chloride ion accumulation at the metal/film interface, lattice expansion on the metal side, undulations at the interface, and structural inhomogeneity on the film side, most of which had previously been rejected by existing models. This work unmasks, at the atomic scale, the mechanism of chloride-induced passivity breakdown that is known to occur in various metallic materials. |
| 学科主题 | Multidisciplinary Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000436958500006 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/80105]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 1.[Zhang, B. 2.Wang, J. 3.Wu, B. 4.Guo, X. W. 5.Wang, Y. J. 6.Chen, D. 7.Zhang, Y. C. 8.Du, K. 9.Ma, X. L.] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Liaoning, Peoples R China 10.[Oguzie, E. E.] Fed Univ Technol Owerri, Electrochem & Mat Sci Res Lab, Dept Chem, Owerri 1526, Nigeria |
| 推荐引用方式 GB/T 7714 | Zhang, B,Wang, J,Wu, B,et al. Unmasking chloride attack on the passive film of metals[J]. NATURE COMMUNICATIONS,2018,9:-. |
| APA | Zhang, B.,Wang, J.,Wu, B.,Guo, XW.,Wang, YJ.,...&Ma, XL.(2018).Unmasking chloride attack on the passive film of metals.NATURE COMMUNICATIONS,9,-. |
| MLA | Zhang, B,et al."Unmasking chloride attack on the passive film of metals".NATURE COMMUNICATIONS 9(2018):-. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。