SPEEK Membrane of Ultrahigh Stability Enhanced by Functionalized Carbon Nanotubes for Vanadium Redox Flow Battery
文献类型:期刊论文
作者 | Ding, M; Ling, X1; Yuan, D2; Cheng, YH; Wu, C; Chao, ZS; Sun, LD; Yang, CW; Jia, CK |
刊名 | FRONTIERS IN CHEMISTRY
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出版日期 | 2018-07-26 |
卷号 | 6页码:- |
关键词 | redox flow battery vanadium redox flow battery ion exchange membrane sulfonated poly(ether ether ketone) carbon nanotube |
ISSN号 | 2296-2646 |
DOI | 10.3389/fchem.2018.00286 |
英文摘要 | Proton exchange membrane is the key factor of vanadium redox flow battery (VRB) as their stability largely determine the lifetime of the VRB. In this study, a SPEEK/MWCNTs-OH composite membrane with ultrahigh stability is constructed by blending sulfonated poly(ether ether ketone) (SPEEK) with multi-walled carbon nanotubes toward VRB application. The carbon nanotubes disperse homogeneously in the SPEEK matrix with the assistance of hydroxyl group. The blended membrane exhibits 94.2 and 73.0% capacity retention after 100 and 500 cycles, respectively in a VRB single cell with coulombic efficiency of over 99.4% at 60 mA cm(-2) indicating outstanding capability of reducing the permeability of vanadium ions and enhancing the transport of protons. The ultrahigh stability and low cost of the composite membrane make it a competent candidate for the next generation larger-scale vanadium redox flow battery. |
学科主题 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000439805400001 |
源URL | [http://ir.imr.ac.cn/handle/321006/80091] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
作者单位 | 1.Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha, Hunan, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang, Liaoning, Peoples R China 3.Natl Univ Singapore, Dept Mat Sci & Engn, Fac Engn, Singapore, Singapore 4.Chongqing Univ, Sch Mat Sci & Engn, State Key Lab Mech Transmiss, Chongqing, Peoples R China 5.Nankai Univ, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin, Peoples R China |
推荐引用方式 GB/T 7714 | Ding, M,Ling, X,Yuan, D,et al. SPEEK Membrane of Ultrahigh Stability Enhanced by Functionalized Carbon Nanotubes for Vanadium Redox Flow Battery[J]. FRONTIERS IN CHEMISTRY,2018,6:-. |
APA | Ding, M.,Ling, X.,Yuan, D.,Cheng, YH.,Wu, C.,...&Jia, CK.(2018).SPEEK Membrane of Ultrahigh Stability Enhanced by Functionalized Carbon Nanotubes for Vanadium Redox Flow Battery.FRONTIERS IN CHEMISTRY,6,-. |
MLA | Ding, M,et al."SPEEK Membrane of Ultrahigh Stability Enhanced by Functionalized Carbon Nanotubes for Vanadium Redox Flow Battery".FRONTIERS IN CHEMISTRY 6(2018):-. |
入库方式: OAI收割
来源:金属研究所
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