中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Influence of oxygen on the glass formation of Mo-O binary alloys

文献类型:期刊论文

作者Duan, FH; Lin, Y; Pan, J; Wang, YX; Yao, JH; Li, Y
刊名JOURNAL OF NON-CRYSTALLINE SOLIDS
出版日期2018-11-15
卷号500页码:210-216
ISSN号0022-3093
关键词Amorphous alloys Oxygen-bearing Glass forming ability Electrodeposition Refractory metal
DOI10.1016/j.jnoncrysol.2018.07.064
英文摘要Oxygen has usually been considered to be detrimental for the glass formation ability and rarely been taken as a main constituent of amorphous alloys. Here, the effect of oxygen on the glass formation of electrodeposited Mo-O binary alloys was systematically investigated by regulating the current density, and the existence of oxygen was found to promote and stabilize the glassy structure. Fully amorphous structure is obtained at the composition of 76 at.% Mo and 24 at.% O, which is close to the Mo-O binary eutectic point. With an increase in the current density from 0.4 to 2.5 A/cm(2), the oxygen content of the deposited films decreases from 24 to 14 at. %, leading to a transition in microstructure from fully amorphous to mixed amorphous/nanocrystalline. In addition, the crystallization behavior and mechanical properties of the as-deposited amorphous Mo76O24 films were studied. The present work not only shows a novel method for producing amorphous alloy with a high refractory metal and oxygen content, but also verifies that oxygen could act as a main constituent in the formation of amorphous alloys.
学科主题Materials Science, Ceramics ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000447096600027
源URL[http://ir.imr.ac.cn/handle/321006/79822]  
专题金属研究所_中国科学院金属研究所
作者单位1.[Duan, F. H.
2.Lin, Y.
3.Pan, J.
4.Wang, Y. X.
5.Yao, J. H.
6.Li, Y.] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
7.[Duan, F. H.
8.Lin, Y.] Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Duan, FH,Lin, Y,Pan, J,et al. Influence of oxygen on the glass formation of Mo-O binary alloys[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS,2018,500:210-216.
APA Duan, FH,Lin, Y,Pan, J,Wang, YX,Yao, JH,&Li, Y.(2018).Influence of oxygen on the glass formation of Mo-O binary alloys.JOURNAL OF NON-CRYSTALLINE SOLIDS,500,210-216.
MLA Duan, FH,et al."Influence of oxygen on the glass formation of Mo-O binary alloys".JOURNAL OF NON-CRYSTALLINE SOLIDS 500(2018):210-216.

入库方式: OAI收割

来源:金属研究所

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