Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating
文献类型：期刊论文
| 作者 | Zhang, YJ; Wang, ZJ; Chen, YN; Zhang, ZD; Wang, ZJ (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. |
| 刊名 | JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
 |
| 出版日期 | 2018 |
| 卷号 | 38期号:1页码:105-111 |
| 关键词 | Titanate Thin-films Low-temperature In-situ State Photocatalysis Precursors Chemistry Ceramics Graphene Equation |
| ISSN号 | 0955-2219 |
| 英文摘要 | Lead titanate (PTO) films were deposited onto Pt/Ti/SiO2/Si substrates by a sol-gel method and annealed by microwave irradiation and conventional heating. In contrast to conventional heating, microwave irradiation can crystallize the PTO films at a low temperature of 450 degrees C or at 550 degrees C for only 5 min. The XRD and TEM studies reveal that microwave radiation can reduce the nucleation time, and increase the growth rate of perovskite grains in the crystallization process. Moreover, the results using the Avrami's model show that the effective activation energy for crystallization process by microwave irradiation is 131 kJ/mol, much lower than that for the PTO films by conventional heating (216 kJ/mol). Therefore, microwave irradiation can reduce the effective activation energy for the nucleation and grain growth of the perovskite phase during the crystallization process, contributing to a low-temperature or a short-time preparation process of ferroelectric films.; Lead titanate (PTO) films were deposited onto Pt/Ti/SiO2/Si substrates by a sol-gel method and annealed by microwave irradiation and conventional heating. In contrast to conventional heating, microwave irradiation can crystallize the PTO films at a low temperature of 450 degrees C or at 550 degrees C for only 5 min. The XRD and TEM studies reveal that microwave radiation can reduce the nucleation time, and increase the growth rate of perovskite grains in the crystallization process. Moreover, the results using the Avrami's model show that the effective activation energy for crystallization process by microwave irradiation is 131 kJ/mol, much lower than that for the PTO films by conventional heating (216 kJ/mol). Therefore, microwave irradiation can reduce the effective activation energy for the nucleation and grain growth of the perovskite phase during the crystallization process, contributing to a low-temperature or a short-time preparation process of ferroelectric films. |
| 学科主题 | Materials Science, Ceramics |
| 语种 | 英语 |
| 资助机构 | Hundred Talents Program of Chinese Academy of Sciences; National Natural Science of Foundation of China [51172238, 51502303] |
| 公开日期 | 2018-06-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/79629]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wang, ZJ (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Zhang, YJ,Wang, ZJ,Chen, YN,et al. Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,2018,38(1):105-111. |
| APA | Zhang, YJ,Wang, ZJ,Chen, YN,Zhang, ZD,&Wang, ZJ .(2018).Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating.JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,38(1),105-111. |
| MLA | Zhang, YJ,et al."Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating".JOURNAL OF THE EUROPEAN CERAMIC SOCIETY 38.1(2018):105-111. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。