Electrochemically substituted metal phthalocyanines, e-MPc (M = Co, Ni), as highly active and selective catalysts for CO2 reduction
文献类型：期刊论文
| 作者 | Cheng, Y; Veder, JP; Thomsen, L; Zhao, SY; Saunders, M; Demichelis, R; Liu, C; De Marco, R; Jiang, SP; Jiang, SP (reprint author), Curtin Univ, Dept Chem Engn, Fuels & Energy Technol Inst, Perth, WA 6102, Australia. |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2018-01-28 |
| 卷号 | 6期号:4页码:1370-1375 |
| ISSN号 | 2050-7488 |
| 关键词 | Carbon-dioxide Iron(0) Porphyrins Cobalt Porphyrins Au Nanoparticles Conversion Electroreduction Water Efficient Cations Issues |
| 英文摘要 | Metal-oxide nanoclusters (NCs) such as FeOx, CoOx, and NiOx are incorporated into iron phthalocyanine (FePc) supported on graphene, MOx/FePc, via a facile self-assembly method. MOx/FePc electrocatalysts show high activity, selectivity and stability for the electrochemical CO2 reduction reaction (CO2RR) as compared with the corresponding metal phthalocyanines, i.e., FePc, CoPc and NiPc, under identical test conditions. Near edge X-ray absorption fine structure (NEXAFS) spectroscopy reveals that MOx/FePc undergoes a metal ion replacement of the iron center of Pc, forming electrochemically substituted metal Pc, e-MPc where M = Co and Ni, coexisting with the replaced FeOx nanoparticles (NPs) in the vicinity of the e-MPc. The results indicate that the e-MPc with in situ dispersed FeOx NPs, FeOx/e-CoPc and FeOx/e-NiPc exhibits excellent activity, high selectivity and stability for the CO2RR.; Metal-oxide nanoclusters (NCs) such as FeOx, CoOx, and NiOx are incorporated into iron phthalocyanine (FePc) supported on graphene, MOx/FePc, via a facile self-assembly method. MOx/FePc electrocatalysts show high activity, selectivity and stability for the electrochemical CO2 reduction reaction (CO2RR) as compared with the corresponding metal phthalocyanines, i.e., FePc, CoPc and NiPc, under identical test conditions. Near edge X-ray absorption fine structure (NEXAFS) spectroscopy reveals that MOx/FePc undergoes a metal ion replacement of the iron center of Pc, forming electrochemically substituted metal Pc, e-MPc where M = Co and Ni, coexisting with the replaced FeOx nanoparticles (NPs) in the vicinity of the e-MPc. The results indicate that the e-MPc with in situ dispersed FeOx NPs, FeOx/e-CoPc and FeOx/e-NiPc exhibits excellent activity, high selectivity and stability for the CO2RR. |
| 学科主题 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| 资助机构 | Australian Research Council [DP180100568, DP180100731, DP150102044, DP150102025]; Australian Research Council LIEF grant [LE120100026] |
| 公开日期 | 2018-06-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/79563]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Jiang, SP (reprint author), Curtin Univ, Dept Chem Engn, Fuels & Energy Technol Inst, Perth, WA 6102, Australia. |
| 推荐引用方式 GB/T 7714 | Cheng, Y,Veder, JP,Thomsen, L,et al. Electrochemically substituted metal phthalocyanines, e-MPc (M = Co, Ni), as highly active and selective catalysts for CO2 reduction[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(4):1370-1375. |
| APA | Cheng, Y.,Veder, JP.,Thomsen, L.,Zhao, SY.,Saunders, M.,...&Jiang, SP .(2018).Electrochemically substituted metal phthalocyanines, e-MPc (M = Co, Ni), as highly active and selective catalysts for CO2 reduction.JOURNAL OF MATERIALS CHEMISTRY A,6(4),1370-1375. |
| MLA | Cheng, Y,et al."Electrochemically substituted metal phthalocyanines, e-MPc (M = Co, Ni), as highly active and selective catalysts for CO2 reduction".JOURNAL OF MATERIALS CHEMISTRY A 6.4(2018):1370-1375. |
入库方式： OAI收割
来源：金属研究所
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