Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism
文献类型：期刊论文
| 作者 | Gupta, N; Khavryuchenko, O; Wen, GD; Wu, KH; Su, DS; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. |
| 刊名 | CARBON
 |
| 出版日期 | 2018-04-01 |
| 卷号 | 130页码:714-723 |
| 关键词 | Metal-free Catalyst Carbon Nanotubes Oxidative Dehydrogenation Graphene Oxide Hydrazine Efficient Nanodiamonds Exchange Glycerol Benzene |
| ISSN号 | 0008-6223 |
| 英文摘要 | Carbon is demonstrated as a mild and transition metal free catalyst for the preparation of N-rich heterocyclic compounds for the first time. The surface > C=O groups on nanodiamonds were identified as an active site, which most probably generates imidogene as a reactive species that triggers the reaction. The experimental results supported with density functional theory calculations were used to reveal a new reaction pathway, different from the conventional homogeneous one that indicates involvement of nitrogen radicals in the reaction. (c) 2018 Elsevier Ltd. All rights reserved.; Carbon is demonstrated as a mild and transition metal free catalyst for the preparation of N-rich heterocyclic compounds for the first time. The surface > C=O groups on nanodiamonds were identified as an active site, which most probably generates imidogene as a reactive species that triggers the reaction. The experimental results supported with density functional theory calculations were used to reveal a new reaction pathway, different from the conventional homogeneous one that indicates involvement of nitrogen radicals in the reaction. (c) 2018 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry, Physical ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| 资助机构 | Chinese Academy of Sciences [2014FFGB0006]; National Natural Science Foundation of China [21503241, 21473223, 51521091] |
| 公开日期 | 2018-06-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/79413]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Gupta, N,Khavryuchenko, O,Wen, GD,et al. Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism[J]. CARBON,2018,130:714-723. |
| APA | Gupta, N,Khavryuchenko, O,Wen, GD,Wu, KH,Su, DS,&Su, DS .(2018).Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism.CARBON,130,714-723. |
| MLA | Gupta, N,et al."Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism".CARBON 130(2018):714-723. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。