Developing beta-type bulk metallic glass composites from Ti/Zr-based bulk metallic glasses by an iteration method
文献类型:期刊论文
作者 | Zhang, L; Fu, HM; Li, H; Zhu, ZW; Zhang, HW; Li, WR; Li, YD; Zhang, HF; Zhang, HF (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS |
出版日期 | 2018-04-05 |
卷号 | 740页码:639-646 |
ISSN号 | 0925-8388 |
关键词 | Situ Neutron-diffraction Matrix Composites Mechanical-properties Phase-transformation Tensile Properties Ti Plasticity Ductility Crystallization Microstructure |
英文摘要 | Bulk metallic glass composites containing in-situ formed beta-Ti/Zr phases (beta-type BMGCs), which exhibit a good combination of strength and plasticity, were generally developed by adding beta-stabilizers, such as Nb, Ta, V, etc., into Ti/Zr-based bulk metallic glasses (BMGs). In this work, an iteration method is proposed to develop beta-type BMGCs from Ti/Zr-based BMGs, and the compositions of BMGCs can be designed by "the composition of in-situ formed beta phase (the iterative variable) + the composition of BMG". Due to the fast elemental diffusions between the beta phase and the (supercooled) liquid phase, the iteration method can develop beta-type BMGCs in which both phases can maintain a mutual (metastable) equilibrium during solidification. The procedures of the iteration method and its underlying thermodynamic and kinetic principles are discussed, and a Zr56.9Ti18.8Cu7.4Ni5.7Be11.3 BMGC was developed from Vitreloy 1 by using the iterative method. As compared with beta-type BMGCs developed by the conventional method, beta-type BMGCs developed by the iteration method have two advantages: (i) the good glassforming ability of the initial BMGs can be largely inherited by the glassy matrices in BMGCs; (ii) without adding beta-stabilizers, the in-situ formed beta phases are more likely to be metastable. The current iteration method is of scientific significance on improving plasticity of Ti/Zr-based BMGs and developing new beta-type BMGCs. (C) 2018 Elsevier B.V. All rights reserved.; Bulk metallic glass composites containing in-situ formed beta-Ti/Zr phases (beta-type BMGCs), which exhibit a good combination of strength and plasticity, were generally developed by adding beta-stabilizers, such as Nb, Ta, V, etc., into Ti/Zr-based bulk metallic glasses (BMGs). In this work, an iteration method is proposed to develop beta-type BMGCs from Ti/Zr-based BMGs, and the compositions of BMGCs can be designed by "the composition of in-situ formed beta phase (the iterative variable) + the composition of BMG". Due to the fast elemental diffusions between the beta phase and the (supercooled) liquid phase, the iteration method can develop beta-type BMGCs in which both phases can maintain a mutual (metastable) equilibrium during solidification. The procedures of the iteration method and its underlying thermodynamic and kinetic principles are discussed, and a Zr56.9Ti18.8Cu7.4Ni5.7Be11.3 BMGC was developed from Vitreloy 1 by using the iterative method. As compared with beta-type BMGCs developed by the conventional method, beta-type BMGCs developed by the iteration method have two advantages: (i) the good glassforming ability of the initial BMGs can be largely inherited by the glassy matrices in BMGCs; (ii) without adding beta-stabilizers, the in-situ formed beta phases are more likely to be metastable. The current iteration method is of scientific significance on improving plasticity of Ti/Zr-based BMGs and developing new beta-type BMGCs. (C) 2018 Elsevier B.V. All rights reserved. |
学科主题 | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
资助机构 | National Natural Science Foundation of China [51434008, 51790484, 51701213, U1738101]; China's Manned Space Station Project [TGJZ800-2-RW024]; CAS Key Project "Research & Development of Nuclear Materials and Service Safety Assurance Technology [ZDRW-CN-2017-1]; Shenyang Key R & D and Technology Transfer Program [Z17-7-001]; Theme Special Project of Shenyang Key Science and Technology Research and Development Programs [17-85-0-00]; Science and Technology Planning Project of Guangdong Province, China [2015B090926001]; Dongguan Innovative Research Team Program [2014607134] |
公开日期 | 2018-06-05 |
源URL | [http://ir.imr.ac.cn/handle/321006/79375] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Zhang, HF (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China. |
推荐引用方式 GB/T 7714 | Zhang, L,Fu, HM,Li, H,et al. Developing beta-type bulk metallic glass composites from Ti/Zr-based bulk metallic glasses by an iteration method[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2018,740:639-646. |
APA | Zhang, L.,Fu, HM.,Li, H.,Zhu, ZW.,Zhang, HW.,...&Zhang, HF .(2018).Developing beta-type bulk metallic glass composites from Ti/Zr-based bulk metallic glasses by an iteration method.JOURNAL OF ALLOYS AND COMPOUNDS,740,639-646. |
MLA | Zhang, L,et al."Developing beta-type bulk metallic glass composites from Ti/Zr-based bulk metallic glasses by an iteration method".JOURNAL OF ALLOYS AND COMPOUNDS 740(2018):639-646. |
入库方式: OAI收割
来源:金属研究所
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