Al-water reactivity of Al-Mg-Ga-In-Sn alloys used for hydraulic fracturing tools
文献类型:期刊论文
作者 | Du, BD; He, TT; Liu, GL; Chen, W; Wang, YM; Wang, W; Chen, DM; Chen, DM (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China. |
刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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出版日期 | 2018-04-12 |
卷号 | 43期号:15页码:7201-7215 |
关键词 | Corrosion Behavior Hydrogen Generation Mechanical-properties Aluminum-alloys Rich Alloys High-strength Cu Alloys Microstructure Magnesium Ball |
ISSN号 | 0360-3199 |
英文摘要 | In order to develop a new kind of dissolvable alloy used for hydraulic fracturing tools, a series of Al-Mg-Ga-In-Sn alloys with different Mg contents were prepared by smelting and casting methods to investigate the effect of Mg on the reactivity of alloys with water. Their microstructures were investigated by means of XRD and SEM. The Volta potential difference (Delta VPD) of the interfacial phases with Al was measured using AFM/SKPFM. Mg forms different intermetallic compounds with low melting point metals, depending on Mg additions in alloys. Different from the formation of In3Sn phase in Al-Ga-In-Sn alloys, the In3Sn phase disappears in Mg-bearing alloys. The experiments found that the reactivities of Mg-bearing alloys with water are closely related to Mg content of alloys and water temperature. The alloys react with water slowly at the beginning of reaction, following with a fast reaction. From the corrosive morphologies of alloys, the precipitation of low melting point metals from interfacial phases was observed at Al grain boundaries. The lower electric potential of interfacial phases than Al was accounted for the precipitation of low melting point metals, because the interfacial phases form micro-galvanic cells with Al when alloys contact with water. A reaction mechanism of Mg-bearing alloys with water was proposed to explain the reactivties of alloys with water. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.; In order to develop a new kind of dissolvable alloy used for hydraulic fracturing tools, a series of Al-Mg-Ga-In-Sn alloys with different Mg contents were prepared by smelting and casting methods to investigate the effect of Mg on the reactivity of alloys with water. Their microstructures were investigated by means of XRD and SEM. The Volta potential difference (Delta VPD) of the interfacial phases with Al was measured using AFM/SKPFM. Mg forms different intermetallic compounds with low melting point metals, depending on Mg additions in alloys. Different from the formation of In3Sn phase in Al-Ga-In-Sn alloys, the In3Sn phase disappears in Mg-bearing alloys. The experiments found that the reactivities of Mg-bearing alloys with water are closely related to Mg content of alloys and water temperature. The alloys react with water slowly at the beginning of reaction, following with a fast reaction. From the corrosive morphologies of alloys, the precipitation of low melting point metals from interfacial phases was observed at Al grain boundaries. The lower electric potential of interfacial phases than Al was accounted for the precipitation of low melting point metals, because the interfacial phases form micro-galvanic cells with Al when alloys contact with water. A reaction mechanism of Mg-bearing alloys with water was proposed to explain the reactivties of alloys with water. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
学科主题 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
语种 | 英语 |
资助机构 | Foundation of Chinese Academic of Sciences [CXJJ-17-M158] |
公开日期 | 2018-06-05 |
源URL | [http://ir.imr.ac.cn/handle/321006/79365] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Wang, W; Chen, DM (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China. |
推荐引用方式 GB/T 7714 | Du, BD,He, TT,Liu, GL,et al. Al-water reactivity of Al-Mg-Ga-In-Sn alloys used for hydraulic fracturing tools[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2018,43(15):7201-7215. |
APA | Du, BD.,He, TT.,Liu, GL.,Chen, W.,Wang, YM.,...&Chen, DM .(2018).Al-water reactivity of Al-Mg-Ga-In-Sn alloys used for hydraulic fracturing tools.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,43(15),7201-7215. |
MLA | Du, BD,et al."Al-water reactivity of Al-Mg-Ga-In-Sn alloys used for hydraulic fracturing tools".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 43.15(2018):7201-7215. |
入库方式: OAI收割
来源:金属研究所
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