Phosphorus-assisted solid-phase approach to three-dimensional highly porous graphene sheets and their capacitance properties
文献类型：期刊论文
| 作者 | Chen, CL; Liang, T; Chen, X; Zhang, BS; Wang, L; Zhang, J; Zhang, J (reprint author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China. |
| 刊名 | CARBON
 |
| 出版日期 | 2018-06-01 |
| 卷号 | 132页码:8-15 |
| 关键词 | Oxygen Reduction Reaction Electrode Material Doped Graphene Energy-storage Surface-area Carbon Supercapacitors Monoliths Networks Foams |
| ISSN号 | 0008-6223 |
| 英文摘要 | Although graphene has emerged as a promising candidate for constructing a high-performance super-capacitor electrode, its electrochemical performance has been restricted by the irreversible layer-restacking or aggregation. Here we report that a simple solid-phase pyrolysis approach to fabricate 3D highly porous and self-supporting graphene sheets under the assistance of thermal sensitive amidinourea phosphate served as the inserting and sacrificing template. The as-synthesized 3D graphene architecture features with ultralight, fire-resistant, heteroatoms incorporated and hierarchically porous characteristics as well as other specific properties, being a very promising metal-free material for various applications. Employing as an electrode material in supercapacitor, the 3D architecture combines wrinkled graphene layers, hierarchical interlayer pores, and defects or vacancies in graphene sheets, are very beneficial to resist layer stacking, minimize ions diffusion resistance and enhance intrinsic capacitance. By introducing phosphorus sacrificing template, the product delivered an approximate 2.7 folds higher specific capacitance with faster ionic and electronic transport than that of the counterpart synthesized without phosphorus participation. (C) 2018 Elsevier Ltd. All rights reserved.; Although graphene has emerged as a promising candidate for constructing a high-performance super-capacitor electrode, its electrochemical performance has been restricted by the irreversible layer-restacking or aggregation. Here we report that a simple solid-phase pyrolysis approach to fabricate 3D highly porous and self-supporting graphene sheets under the assistance of thermal sensitive amidinourea phosphate served as the inserting and sacrificing template. The as-synthesized 3D graphene architecture features with ultralight, fire-resistant, heteroatoms incorporated and hierarchically porous characteristics as well as other specific properties, being a very promising metal-free material for various applications. Employing as an electrode material in supercapacitor, the 3D architecture combines wrinkled graphene layers, hierarchical interlayer pores, and defects or vacancies in graphene sheets, are very beneficial to resist layer stacking, minimize ions diffusion resistance and enhance intrinsic capacitance. By introducing phosphorus sacrificing template, the product delivered an approximate 2.7 folds higher specific capacitance with faster ionic and electronic transport than that of the counterpart synthesized without phosphorus participation. (C) 2018 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry, Physical ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| 资助机构 | National Natural Science Foundation of China [51422212, 21403261]; Chinese Academy of Sciences [QYZDB-SSW-JSC037, ZDRW-CN-2016-1]; Science and Technology Department of Zhejiang Province [2015C31118]; Zhejiang Provincial Natural Science Foundation of China [LR16B030001]; International Science and Technology Cooperation Program of Ningbo City [2014D10004]; K.C. Wong Education Foundation [rczx0800] |
| 公开日期 | 2018-06-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/79298]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Chen, CL; Zhang, J (reprint author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Chen, CL,Liang, T,Chen, X,et al. Phosphorus-assisted solid-phase approach to three-dimensional highly porous graphene sheets and their capacitance properties[J]. CARBON,2018,132:8-15. |
| APA | Chen, CL.,Liang, T.,Chen, X.,Zhang, BS.,Wang, L.,...&Zhang, J .(2018).Phosphorus-assisted solid-phase approach to three-dimensional highly porous graphene sheets and their capacitance properties.CARBON,132,8-15. |
| MLA | Chen, CL,et al."Phosphorus-assisted solid-phase approach to three-dimensional highly porous graphene sheets and their capacitance properties".CARBON 132(2018):8-15. |
入库方式： OAI收割
来源：金属研究所
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