Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes
文献类型：期刊论文
| 作者 | Gupta, Neeraj; Khavryuchenko, Oleksiy; Villa, Alberto; Su, Dangsheng; Su, DS (reprint author), Chinese Acad Sci, Catalysis Div, IMR Shenyang Natl Lab, Shenyang 110016, Liaoning, Peoples R China.; Villa, A (reprint author), Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China. |
| 刊名 | WILEY-V C H VERLAG GMBH
 |
| 出版日期 | 2017-08-10 |
| 卷号 | 10期号:15页码:3030-3034 |
| 关键词 | Biomass Conversion Carbon Nanotubes Glycerol Metal-free Oxidation Ncnts |
| ISSN号 | 1864-5631 |
| 英文摘要 | Nitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process.; Nitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process. |
| 学科主题 | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology |
| 语种 | 英语 |
| 资助机构 | Chinese Academy of Sciences [2014FFGB0006]; Universita degli Studi di Milano, "Piano di sviluppo d'ateneo, Linea 2 Azione A" |
| 公开日期 | 2018-01-10 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/79153]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Su, DS (reprint author), Chinese Acad Sci, Catalysis Div, IMR Shenyang Natl Lab, Shenyang 110016, Liaoning, Peoples R China.; Villa, A (reprint author), Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Gupta, Neeraj,Khavryuchenko, Oleksiy,Villa, Alberto,et al. Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes[J]. WILEY-V C H VERLAG GMBH,2017,10(15):3030-3034. |
| APA | Gupta, Neeraj.,Khavryuchenko, Oleksiy.,Villa, Alberto.,Su, Dangsheng.,Su, DS .,...&Su, DS .(2017).Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes.WILEY-V C H VERLAG GMBH,10(15),3030-3034. |
| MLA | Gupta, Neeraj,et al."Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes".WILEY-V C H VERLAG GMBH 10.15(2017):3030-3034. |
入库方式： OAI收割
来源：金属研究所
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