Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond
文献类型：期刊论文
| 作者 | Lin, Yangming; Wu, Kuang-Hsu (Tim); Yu, Linhui; Heumann, Saskia; Su, Dang Sheng; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Fritz Haber Inst Max, Dept Inorgan Chem, Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany. |
| 刊名 | WILEY-V C H VERLAG GMBH
 |
| 出版日期 | 2017-09-11 |
| 卷号 | 10期号:17页码:3497-3505 |
| 关键词 | Alcohols Carbocatalysis Electrochemistry Oxidation Redox Reactions |
| ISSN号 | 1864-5631 |
| 英文摘要 | Selective oxidation of alcohols to aldehydes is widely applicable to the synthesis of various green chemicals. The poor chemoselectivity for complicated primary aldehydes over state-of-the-art metal-free or metal-based catalysts represents a major obstacle for industrial application. Bucky nanodiamond is a potential green catalyst that exhibits excellent chemoselectivity and cycling stability for the selective oxidation of primary alcohols in diverse structures (22examples, including aromatic, substituted aromatic, unsaturated, heterocyclic, and linear chain alcohols) to their corresponding aldehydes. The results are comparable to reported transition-metal catalysts including conventional Pt/C and Ru/C catalysts for certain substrates under solvent-free conditions. The possible activation process of the oxidant and substrates by the surface oxygen groups and defect species are revealed with model catalysts, exsitu electrochemical measurements, and exsitu attenuated total reflectance. The zigzag edges of sp(2) carbon planes are shown to play a key role in these reactions.; Selective oxidation of alcohols to aldehydes is widely applicable to the synthesis of various green chemicals. The poor chemoselectivity for complicated primary aldehydes over state-of-the-art metal-free or metal-based catalysts represents a major obstacle for industrial application. Bucky nanodiamond is a potential green catalyst that exhibits excellent chemoselectivity and cycling stability for the selective oxidation of primary alcohols in diverse structures (22examples, including aromatic, substituted aromatic, unsaturated, heterocyclic, and linear chain alcohols) to their corresponding aldehydes. The results are comparable to reported transition-metal catalysts including conventional Pt/C and Ru/C catalysts for certain substrates under solvent-free conditions. The possible activation process of the oxidant and substrates by the surface oxygen groups and defect species are revealed with model catalysts, exsitu electrochemical measurements, and exsitu attenuated total reflectance. The zigzag edges of sp(2) carbon planes are shown to play a key role in these reactions. |
| 学科主题 | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology |
| 语种 | 英语 |
| 资助机构 | Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09030103] |
| 公开日期 | 2018-01-10 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/79100]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Fritz Haber Inst Max, Dept Inorgan Chem, Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany. |
| 推荐引用方式 GB/T 7714 | Lin, Yangming,Wu, Kuang-Hsu ,Yu, Linhui,et al. Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond[J]. WILEY-V C H VERLAG GMBH,2017,10(17):3497-3505. |
| APA | Lin, Yangming.,Wu, Kuang-Hsu .,Yu, Linhui.,Heumann, Saskia.,Su, Dang Sheng.,...&Su, DS .(2017).Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond.WILEY-V C H VERLAG GMBH,10(17),3497-3505. |
| MLA | Lin, Yangming,et al."Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond".WILEY-V C H VERLAG GMBH 10.17(2017):3497-3505. |
入库方式： OAI收割
来源：金属研究所
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