Alkalized Ti3C2 MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries
文献类型：期刊论文
| 作者 | Lian, Peichao; Dong, Yanfeng; Wu, Zhong-Shuai; Zheng, Shuanghao; Wang, Xiaohui; Wang, Sen; Sun, Chenglin; Qin, Jieqiong; Shi, Xiaoyu; Bao, Xinhe |
| 刊名 | ELSEVIER SCIENCE BV
 |
| 出版日期 | 2017-10-01 |
| 卷号 | 40页码:1-8 |
| 关键词 | Mxene Alkalization Nanoribbons Sodium Ion Batteries Potassium Ion Batteries |
| ISSN号 | 2211-2855 |
| 英文摘要 | As post-lithium ion batteries, both sodium ion batteries (SIBs) and potassium ion batteries (PIBs) possess great potential for large scale energy storage. However, the improvements of both SIBs and PIBs for practical applications are facing great challenges in the development of high-performance electrode materials. Here, we demonstrate the fabrication of alkalized Ti3C2 (a-Ti3C2) MXene nanoribbons attained by continuous shaking treatment of pristine Ti3C2 MXene in aqueous KOH solution. Benefited from the expanded interlayer spacing of a-Ti3C2, narrow widths of nanoribbons as well as three-dimensional interconnected porous frameworks for enhanced ion reaction kinetics and improved structure stability, the resulting a-Ti3C2 anodes showed excellent sodium/potassium storage performance, for example, high reversible capacities of 168 and 136 mA h g(-1) at 20 mA g(-1) and 84 and 78 mA h g(-1) at 200 mA g(-1) were obtained for SIBs and PIBs, respectively. Notably, a-Ti3C2 possessed outstanding long-term cyclability at high current density of 200 mA g(-1), delivering a capacity of similar to 50 mA h g(-1) for SIBs and similar to 42 mA h g(-1) for PIBs after 500 cycles, which outperformed most of reported MXene based anodes for SIBs and PIBs. Moreover, this alkalization strategy could be extended as a universal approach for fabricating various alkalized MXene-based frameworks derived from a large family of MAX phases for numerous applications, such as catalysis, energy storage and conversion.; As post-lithium ion batteries, both sodium ion batteries (SIBs) and potassium ion batteries (PIBs) possess great potential for large scale energy storage. However, the improvements of both SIBs and PIBs for practical applications are facing great challenges in the development of high-performance electrode materials. Here, we demonstrate the fabrication of alkalized Ti3C2 (a-Ti3C2) MXene nanoribbons attained by continuous shaking treatment of pristine Ti3C2 MXene in aqueous KOH solution. Benefited from the expanded interlayer spacing of a-Ti3C2, narrow widths of nanoribbons as well as three-dimensional interconnected porous frameworks for enhanced ion reaction kinetics and improved structure stability, the resulting a-Ti3C2 anodes showed excellent sodium/potassium storage performance, for example, high reversible capacities of 168 and 136 mA h g(-1) at 20 mA g(-1) and 84 and 78 mA h g(-1) at 200 mA g(-1) were obtained for SIBs and PIBs, respectively. Notably, a-Ti3C2 possessed outstanding long-term cyclability at high current density of 200 mA g(-1), delivering a capacity of similar to 50 mA h g(-1) for SIBs and similar to 42 mA h g(-1) for PIBs after 500 cycles, which outperformed most of reported MXene based anodes for SIBs and PIBs. Moreover, this alkalization strategy could be extended as a universal approach for fabricating various alkalized MXene-based frameworks derived from a large family of MAX phases for numerous applications, such as catalysis, energy storage and conversion. |
| 学科主题 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
| 语种 | 英语 |
| 资助机构 | National Key R & D Program of China [2016YBF0100100, 2016YFA0200200]; Thousand Youth Talents Plan of China [Y5061921T3]; National Natural Science Foundation of China [51572259]; Natural Science Foundation of Liaoning Province [201602737]; DICP [Y5610121T3]; China Postdoctoral Science Foundation [2016M601349, 2017T100188] |
| 公开日期 | 2018-01-10 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/79073]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wu, ZS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Lian, Peichao,Dong, Yanfeng,Wu, Zhong-Shuai,et al. Alkalized Ti3C2 MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries[J]. ELSEVIER SCIENCE BV,2017,40:1-8. |
| APA | Lian, Peichao.,Dong, Yanfeng.,Wu, Zhong-Shuai.,Zheng, Shuanghao.,Wang, Xiaohui.,...&Wu, ZS .(2017).Alkalized Ti3C2 MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries.ELSEVIER SCIENCE BV,40,1-8. |
| MLA | Lian, Peichao,et al."Alkalized Ti3C2 MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries".ELSEVIER SCIENCE BV 40(2017):1-8. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。