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Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene
文献类型：期刊论文
| 作者 | Xiang, Sheng-Chang3; Zhang, Zhangjing3; Zhao, Cong-Gui3; Hong, Kunlun4; Zhao, Xuebo5; Ding, De-Rong3; Xie, Ming-Hua6; Wu, Chuan-De6; Das, Madhab C.3; Gill, Rachel5 |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2011-02-01 |
| 卷号 | 2期号:1页码:1～7 |
| 关键词 | POROUS MATERIAL ENANTIOSELECTIVE SEPARATION COORDINATION POLYMER ASYMMETRIC CATALYSIS SORPTION PROPERTIES MOLECULAR-SIEVES ADSORPTION HYDROGENATION BEHAVIOR SOLIDS |
| ISSN号 | 2041-172 |
| 中文摘要 | Separation of acetylene and ethylene is an important industrial process because both compounds are essential reagents for a range of chemical products and materials. Current separation approaches include the partial hydrogenation of acetylene into ethylene over a supported Pd catalyst, and the extraction of cracked olefins using an organic solvent; both routes are costly and energy consuming. Adsorption technologies may allow separation, but microporous materials exhibiting highly selective adsorption of C(2)H(2)/C(2)H(4) have not been realized to date. Here, we report the development of tunable microporous enantiopure mixed-metal-organic framework (M'MOF) materials for highly selective separation of C(2)H(2) and C(2)H(4). The high selectivities achieved suggest the potential application of microporous M'MOFs for practical adsorption-based separation of C(2)H(2)/C(2)H(4). |
| 英文摘要 | Separation of acetylene and ethylene is an important industrial process because both compounds are essential reagents for a range of chemical products and materials. Current separation approaches include the partial hydrogenation of acetylene into ethylene over a supported Pd catalyst, and the extraction of cracked olefins using an organic solvent; both routes are costly and energy consuming. Adsorption technologies may allow separation, but microporous materials exhibiting highly selective adsorption of C(2)H(2)/C(2)H(4) have not been realized to date. Here, we report the development of tunable microporous enantiopure mixed-metal-organic framework (M'MOF) materials for highly selective separation of C(2)H(2) and C(2)H(4). The high selectivities achieved suggest the potential application of microporous M'MOFs for practical adsorption-based separation of C(2)H(2)/C(2)H(4). |
| WOS标题词 | Science & Technology |
| 学科主题 | 储氢及新型纳孔材料 |
| 类目[WOS] | Multidisciplinary Sciences |
| 研究领域[WOS] | Science & Technology - Other Topics |
| 关键词[WOS] | POROUS MATERIAL ; ENANTIOSELECTIVE SEPARATION ; COORDINATION POLYMER ; ASYMMETRIC CATALYSIS ; SORPTION PROPERTIES ; MOLECULAR-SIEVES ; ADSORPTION ; HYDROGENATION ; BEHAVIOR ; SOLIDS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000288225900033 |
| 公开日期 | 2011-09-09 |
| 源URL | [http://ir.qibebt.ac.cn//handle/337004/554]  |
| 专题 | 青岛生物能源与过程研究所_储氢及新型纳孔材料团队 |
| 作者单位 | 1.Newcastle Univ, No Carbon Res Labs, Sir Joseph Swan Inst, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England 2.Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England 3.Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA 4.Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA 5.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 6.Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Sheng-Chang,Zhang, Zhangjing,Zhao, Cong-Gui,et al. Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene[J]. NATURE COMMUNICATIONS,2011,2(1):1～7. |
| APA | Xiang, Sheng-Chang.,Zhang, Zhangjing.,Zhao, Cong-Gui.,Hong, Kunlun.,Zhao, Xuebo.,...&Chen, Banglin.(2011).Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene.NATURE COMMUNICATIONS,2(1),1～7. |
| MLA | Xiang, Sheng-Chang,et al."Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene".NATURE COMMUNICATIONS 2.1(2011):1～7. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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