Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone
文献类型：期刊论文
| 作者 | Xiaobo Pan ; Ai Liu ; Lihui Yao ; Lei Wang ; Jinfeng Zhang ; Jincai Wu ; Xuebo Zhao, Chu-Chieh Lin |
| 刊名 | Inorganic Chemistry Communications
 |
| 出版日期 | 2011 |
| 卷号 | 14期号:1页码:763–766 |
| 关键词 | Hetero-bimetallic complex ε-Caprolactone Catalyst Ring-opening polymerization |
| 中文摘要 | The reaction of 2,2′-ethylidenebis(4,6-di-tert-butylphenol)(EDBP-H2) with sodium, Al(Me)3 and BnOH with a molar of ratio of 1:1:1:1 in THF gives hetero-bimetallic complex of [(EDBP)Al(CH3)(μ2-OBn)Na(THF)3](1) in 85% yield. In order to investigate the different anion effects on the ROP of ε-caprolactone, complexes [(EDBP)2Al][(Li)(THF)2] (2) and [(EDBP)2Al][(Na)(THF)2] (3) were prepared in an analogous manner to that of 1 in 63% and 71% yields respectively. Experimental results show that hetero-bimetallic complex 1 is an efficient catalyst for the ring-opening polymerization of ε-caprolactone. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2011-09-09 |
| 源URL | [http://ir.qibebt.ac.cn//handle/337004/560]  |
| 专题 | 青岛生物能源与过程研究所_储氢及新型纳孔材料团队 |
| 推荐引用方式 GB/T 7714 | Xiaobo Pan,Ai Liu,Lihui Yao,et al. Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone[J]. Inorganic Chemistry Communications,2011,14(1):763–766. |
| APA | Xiaobo Pan.,Ai Liu.,Lihui Yao.,Lei Wang.,Jinfeng Zhang.,...&Xuebo Zhao, Chu-Chieh Lin.(2011).Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone.Inorganic Chemistry Communications,14(1),763–766. |
| MLA | Xiaobo Pan,et al."Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone".Inorganic Chemistry Communications 14.1(2011):763–766. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。