中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
From 1-d to 3-d Supramolecular Structures Derived from Diphenic Acid and Auxiliary Ligands

文献类型:期刊论文

作者Guo, Feng1; Zhang, Xiuling1; Zhu, Baoyong1; Qiu, Jianchao2
刊名JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
出版日期2010-03-01
卷号20期号:1页码:38-45
关键词Coordination polymers Hydrogen bonds Supramolecular structures Co(II) X-ray single crystal diffraction Ni(II) Zn(II) complexes
中文摘要Four novel compounds [Co(Hdpa) (2)(4,4'-bipy)(2)](n) (1), {[Ni(dpa)(2,2'-bipy)(H(2)O)](H(2)O)}(n), (2), [Ni(dpa)(im)(3)](n) (3) and [Zn(dpa)(im)](n) (4) [H(2)dpa = 2,4'-diphenyl-dicarboxylic acid, 4,4'-bipy = 4,4'-bipyridine, 2,2'-bipy = 2,2'-bipyridine and im = imidazole] were synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray crystallography shows that the 2,4'-diphenic acid exhibits three coordination modes to link the metal ions: mu (1) -eta(1): eta(1)/mu (0) -eta(0): eta(0), mu (1)-eta (1): eta (0)/mu (2)-eta (1): eta (1) and mu (1)-eta (1): eta (0)/mu (1)-eta (1): eta (0). Compound 1 has a 1D supramolecular structure. Compounds 2 and 3 are 3D supramolecular structures. Compound 4 is a 2D supramolecular structure. All the compounds, 1-4, are self-assembled to form supramolecular structures through hydrogen bonding interactions.
英文摘要Four novel compounds [Co(Hdpa) (2)(4,4'-bipy)(2)](n) (1), {[Ni(dpa)(2,2'-bipy)(H(2)O)](H(2)O)}(n), (2), [Ni(dpa)(im)(3)](n) (3) and [Zn(dpa)(im)](n) (4) [H(2)dpa = 2,4'-diphenyl-dicarboxylic acid, 4,4'-bipy = 4,4'-bipyridine, 2,2'-bipy = 2,2'-bipyridine and im = imidazole] were synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray crystallography shows that the 2,4'-diphenic acid exhibits three coordination modes to link the metal ions: mu (1) -eta(1): eta(1)/mu (0) -eta(0): eta(0), mu (1)-eta (1): eta (0)/mu (2)-eta (1): eta (1) and mu (1)-eta (1): eta (0)/mu (1)-eta (1): eta (0). Compound 1 has a 1D supramolecular structure. Compounds 2 and 3 are 3D supramolecular structures. Compound 4 is a 2D supramolecular structure. All the compounds, 1-4, are self-assembled to form supramolecular structures through hydrogen bonding interactions.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]FLEXIBLE BIS(IMIDAZOLE) LIGANDS ; COORDINATION POLYMERS ; CRYSTAL-STRUCTURES ; MAGNETIC-PROPERTIES ; FRAMEWORKS ; COMPLEXES ; NETWORKS
收录类别SCI
语种英语
WOS记录号WOS:000274853000006
公开日期2011-09-09
源URL[http://ir.qibebt.ac.cn//handle/337004/600]  
专题青岛生物能源与过程研究所_条件保障部公共实验室
作者单位1.De Zhou Univ, Dept Chem, Dezhou 253023, Shandong, Peoples R China
2.Chinese Acad Sci, Qingdao Inst BioEnergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式
GB/T 7714
Guo, Feng,Zhang, Xiuling,Zhu, Baoyong,et al. From 1-d to 3-d Supramolecular Structures Derived from Diphenic Acid and Auxiliary Ligands[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,2010,20(1):38-45.
APA Guo, Feng,Zhang, Xiuling,Zhu, Baoyong,&Qiu, Jianchao.(2010).From 1-d to 3-d Supramolecular Structures Derived from Diphenic Acid and Auxiliary Ligands.JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,20(1),38-45.
MLA Guo, Feng,et al."From 1-d to 3-d Supramolecular Structures Derived from Diphenic Acid and Auxiliary Ligands".JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 20.1(2010):38-45.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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