Synthesis, Crystal Structure and Luminescence Property of a New (6,3)-Connected Zn(II) Coordination Polymer
文献类型：期刊论文
| 作者 | Wang, Aidong; Qiu, Jianchao; Guo, Feng; Zhang, Xiuling; Liu, Yongliang |
| 刊名 | JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
 |
| 出版日期 | 2010-06-01 |
| 卷号 | 20期号:2页码:293-297 |
| 关键词 | Coordination polymer Hydrothermal synthesis Crystal structure Luminescence |
| ISSN号 | 0904-010-9347-8 |
| 中文摘要 | The 2D coordination polymer, [Zn(dpa)(bpp)] n (H2dpa = 2,4′-biphenyl-dicarboxylic acid, bpp = 1,3-di(4-pyridyl)propane) was prepared by hydrothermal synthesis in the presence of NaOH and characterized by single-crystal X-ray diffraction, FTIR spectra, element analysis and thermal analysis. The crystal structure determination reveals that the carboxylate groups of 2,4′-biphenyldicarboxylic acid are acting as bridging ligands and adopt two coordination modes; bis-monodentate and bidentate chelating. The network consists of a 2D (6,3)-connected architecture. At room temperature the solid-state luminescence spectrum of [Zn(dpa)(bpp)] n shows a blue emission at about 354 nm upon excitation at 333 nm. |
| 英文摘要 | The 2D coordination polymer, [Zn(dpa)(bpp)] (n) (H(2)dpa = 2,4'-biphenyl-dicarboxylic acid, bpp = 1,3-di(4-pyridyl)propane) was prepared by hydrothermal synthesis in the presence of NaOH and characterized by single-crystal X-ray diffraction, FTIR spectra, element analysis and thermal analysis. The crystal structure determination reveals that the carboxylate groups of 2,4'-biphenyldicarboxylic acid are acting as bridging ligands and adopt two coordination modes; bis-monodentate and bidentate chelating. The network consists of a 2D (6,3)-connected architecture. At room temperature the solid-state luminescence spectrum of [Zn(dpa)(bpp)] (n) shows a blue emission at about 354 nm upon excitation at 333 nm. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | METAL-ORGANIC FRAMEWORKS ; HYDROTHERMAL SYNTHESES ; CADMIUM(II) COMPLEXES ; MAGNETIC-PROPERTIES ; ACID ; LIGAND ; CHAIN ; COBALT(II) ; EXAMPLES ; HELIX |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000277284600012 |
| 公开日期 | 2011-09-09 |
| 源URL | [http://ir.qibebt.ac.cn//handle/337004/606]  |
| 专题 | 青岛生物能源与过程研究所_条件保障部公共实验室 |
| 作者单位 | Chinese Acad Sci, Qingdao Inst BioEnergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Aidong,Qiu, Jianchao,Guo, Feng,et al. Synthesis, Crystal Structure and Luminescence Property of a New (6,3)-Connected Zn(II) Coordination Polymer[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,2010,20(2):293-297. |
| APA | Wang, Aidong,Qiu, Jianchao,Guo, Feng,Zhang, Xiuling,&Liu, Yongliang.(2010).Synthesis, Crystal Structure and Luminescence Property of a New (6,3)-Connected Zn(II) Coordination Polymer.JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,20(2),293-297. |
| MLA | Wang, Aidong,et al."Synthesis, Crystal Structure and Luminescence Property of a New (6,3)-Connected Zn(II) Coordination Polymer".JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 20.2(2010):293-297. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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