Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents
文献类型：期刊论文
| 作者 | Xindong Mu
|
| 刊名 | Accepted Manuscript
 |
| 出版日期 | 2011 |
| 卷号 | 11期号:1页码:0-16 |
| 关键词 | Fructose 5-Hydroxymethylfurfural 5-Methoxymethylfurfural Methyl levulinate Amberlyst-15 |
| 中文摘要 | Conversion of fructose into furan derivatives 5-hydroxymethylfurfural (HMF) and 5-methoxymethylfurfural (MMF) is performed in tetrahydrofuran (THF) and methanol-organic solvent systems, catalysed by an acidic resin Amberlyst-15. The melted fructose can be converted into HMF on the surface of the solid resin catalyst in the presence of THF as an extracting phase, which is a good solvent for HMF and other by-products. The solid resin catalyst can be reused eleven times without losing its catalytic ability, with an average HMF yield of approximately 50%. Upon the addition of methanol, the generated HMF can further react with methanol to form MMF, and the total yield of HMF and MMF could be promoted to 65%. GC-MS analysis confirms the formation of a small amount of methyl levulinate in methanolorganic solvent system. |
| 学科主题 | 绿色化学催化 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2011-09-09 |
| 源URL | [http://ir.qibebt.ac.cn//handle/337004/618]  |
| 专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
| 推荐引用方式 GB/T 7714 | Xindong Mu. Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents[J]. Accepted Manuscript,2011,11(1):0-16. |
| APA | Xindong Mu.(2011).Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents.Accepted Manuscript,11(1),0-16. |
| MLA | Xindong Mu."Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents".Accepted Manuscript 11.1(2011):0-16. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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