Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers
文献类型:期刊论文
作者 | Qiu, Xiaoming1; Yu, Kehan1; Lu, Jiabao1; Gao, Chao2; Hou, Chaoqi2![]() |
刊名 | optical materials
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出版日期 | 2008-10-01 |
卷号 | 31期号:2页码:117-121 |
关键词 | Crystal structure Optical properties Lifetime Liquid laser |
ISSN号 | 0925-3467 |
英文摘要 | a liquid solution on the basis of dissolving a novel tetranuclear neodymium complex nd(4)(tta)(10)o(12)h(22) (htta: 2-thenoyltrifluoroacetone) in polytrifluorochloroethylene oil was presented. the molecular structure of the complex was characterized by single-crystal x-ray diffraction. the optical properties of the liquid medium were studied. enhanced emission was observed at 1064 nm when excited at 340 urn due to efficient energy transfer from t-fa to the nd(3+) ions and the mechanism for energy transfer process was discussed in detail. the obtained fluorescent lifetime was 1.7 mu s and the quantum yield value was 0.63%, which compare well with some other organic liquid media reported previously. besides, this liquid shows outstanding properties with no toxicity and causticity, nonvolatility and high stability. (c) 2008 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; technology ; physical sciences |
学科主题 | 物理科学和化学 |
类目[WOS] | materials science, multidisciplinary ; optics |
研究领域[WOS] | materials science ; optics |
关键词[WOS] | rare-earth ions ; radiationless transition ; lanthanide complexes ; optical-fiber ; luminescence ; glass ; nd ; relaxation ; emission ; ligands |
收录类别 | SCI ; EI |
语种 | 英语 |
WOS记录号 | WOS:000261822200001 |
公开日期 | 2011-09-30 |
源URL | [http://ir.opt.ac.cn/handle/181661/11029] ![]() |
专题 | 西安光学精密机械研究所_瞬态光学技术国家重点实验室 |
作者单位 | 1.Fudan Univ, State Key Lab Adv Photon Mat & Devices, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, State Key Lab Transient Opt & Photon, Xian Inst Opt & Precis Mech, Xian 710119, Shaanxi, Peoples R China |
推荐引用方式 GB/T 7714 | Qiu, Xiaoming,Yu, Kehan,Lu, Jiabao,et al. Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers[J]. optical materials,2008,31(2):117-121. |
APA | Qiu, Xiaoming.,Yu, Kehan.,Lu, Jiabao.,Gao, Chao.,Hou, Chaoqi.,...&Peng, Bo.(2008).Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers.optical materials,31(2),117-121. |
MLA | Qiu, Xiaoming,et al."Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers".optical materials 31.2(2008):117-121. |
入库方式: OAI收割
来源:西安光学精密机械研究所
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