中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Tailoring of Cu@Graphitic Carbon Nanostructures Enables the Selective Detection of Copper Ions and Highly Efficient Catalysis of Organic Pollutants

文献类型:期刊论文

作者Hu, Rui1,2; Furukawa, Taiki3; Gong, Yi1,2; Chen, Lin1,2; Wang, Xiangke4; Tian, Xingyou1,2; Nagatsu, Masaaki3,5,6
刊名ADVANCED MATERIALS INTERFACES
出版日期2018-08-23
卷号5期号:16页码:13
关键词catalysis copper nanomaterials core/shell nanostructures localized surface plasmon resonance structure-property relationships surface modification
ISSN号2196-7350
DOI10.1002/admi.201800551
通讯作者Nagatsu, Masaaki(nagatsu.masaaki@shizuoka.ac.jp)
英文摘要Exploitation of plasmonic nanomaterials with high efficiency and selectivity presents the most significant challenge for their potential applications. A one-step arc discharge to synthesize graphitic carbon-encapsulated copper nanomaterials (Cu@G NMs) functionalized with nitrogen-containing groups uniformly is reported. Combined with the temporal optical emission spectra, it is found that the NH3 introduces H radicals to tailor the core/shell nanostructures of Cu@G NMs inducing the morphological evolution from spherical nanoparticles (NPs) to linear nanowires (NWs), as well as provides dissociated nitrogen-containing species (amino N, pyridinic N, pyrrolic N, and quaternary N) to construct the surface nanoarchitectures. With a localized surface plasmon resonance-based method, the trace Cu2+ ions can be detected rapidly with excellent sensitivity (as low as 10 x 10(-6) M linearly) and selectivity against other metal ions by Cu@G NPs in water samples. Moreover, remarkably enhanced catalytic activities for the reduction of aromatic organic pollutants (i.e., 4-nitrophenol, methylene blue, and methyl orange) are also achieved by Cu@G NWs. This strategy enables the synergistic integration of efficient/selective adsorption capability of graphene shells and plasmonic/catalytic multifunctions of Cu cores in Cu@G platform, exhibiting a great potential in environmental monitoring and management.
WOS关键词ARC-DISCHARGE METHOD ; GOLD NANOPARTICLES ; 4-NITROPHENOL REDUCTION ; PERFORMANCE ; GRAPHENE ; GROWTH ; SHELL ; NANOCRYSTALS ; STABILITY ; NANOTUBES
资助项目Japan Society for the Promotion of Science (JSPS)[16K13709] ; Hosokawa Powder Technology Foundation ; CAS Pioneer Hundred Talents Program ; National Natural Science Foundation of China[51502293] ; Hamamatsu Campus Center for Instrumental Analysis of Shizuoka University
WOS研究方向Chemistry ; Materials Science
语种英语
WOS记录号WOS:000442489600021
出版者WILEY
资助机构Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Japan Society for the Promotion of Science (JSPS) ; Hosokawa Powder Technology Foundation ; Hosokawa Powder Technology Foundation ; Hosokawa Powder Technology Foundation ; Hosokawa Powder Technology Foundation ; Hosokawa Powder Technology Foundation ; 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源URL[http://ir.hfcas.ac.cn:8080/handle/334002/38097]  
专题合肥物质科学研究院_应用技术研究所
通讯作者Nagatsu, Masaaki
作者单位1.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Appl Technol, Hefei 230088, Anhui, Peoples R China
2.Chinese Acad Sci, CAS Key Lab Photovolta & Energy Conservat Mat, Hefei 230031, Anhui, Peoples R China
3.Shizuoka Univ, Grad Sch Integrated Sci & Technol, Dept Engn, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328561, Japan
4.North China Elect Power Univ, Sch Environm & Chem Engn, Beijing 102206, Peoples R China
5.Shizuoka Univ, Grad Sch Sci & Technol, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328561, Japan
6.Shizuoka Univ, Res Inst Elect, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328561, Japan
推荐引用方式
GB/T 7714
Hu, Rui,Furukawa, Taiki,Gong, Yi,et al. Tailoring of Cu@Graphitic Carbon Nanostructures Enables the Selective Detection of Copper Ions and Highly Efficient Catalysis of Organic Pollutants[J]. ADVANCED MATERIALS INTERFACES,2018,5(16):13.
APA Hu, Rui.,Furukawa, Taiki.,Gong, Yi.,Chen, Lin.,Wang, Xiangke.,...&Nagatsu, Masaaki.(2018).Tailoring of Cu@Graphitic Carbon Nanostructures Enables the Selective Detection of Copper Ions and Highly Efficient Catalysis of Organic Pollutants.ADVANCED MATERIALS INTERFACES,5(16),13.
MLA Hu, Rui,et al."Tailoring of Cu@Graphitic Carbon Nanostructures Enables the Selective Detection of Copper Ions and Highly Efficient Catalysis of Organic Pollutants".ADVANCED MATERIALS INTERFACES 5.16(2018):13.

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来源:合肥物质科学研究院

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