The experiments of two-alpha emission from Ne-17,Ne-18 excited levels were performed at the HIRFL-RIBLL facility of the Institute of Modern Physics, Lanzhou. The beams of Ne-17 at the energy of 49.9 MeV/u and Ne-18 at 51.8 MeV/u bombarded a Au-197 target to populate excited states of Ne-17,Ne-18 via Coulomb excitation. Complete kinematics measurements were achieved by the detectors of a silicon strip and CsI+PIN array. The experimental results combined with simple MC simulations show the characteristic of sequential two-alpha emission via O-14 excited states for Ne-18. The results of two-alpha emission from Ne-17 are preliminary and need further analyses.