Crystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)(6)] center dot 4H(2)O (Ln = lanthanide)
文献类型：期刊论文
| 作者 | Zhou, Xianju1,2; Wong, Wing-Tak3; Faucher, Michele D.; Tanner, Peter A.1 |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2008-11-01 |
| 卷号 | 181页码:3057-3064 |
| 关键词 | Bond distance Lanthanide contraction Infrared spectra Crystal structure Covalo-electrostatic model |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2008.08.008 |
| 英文摘要 | Along with crystallographic data of Ln[Fe(CN)(6)]center dot 4H(2)O (Ln = lanthanide), the infrared spectra are reassigned to examine bond length trends across the series of Ln. The changes in mean Ln-O, Ln-N, C N and Fe-C distances are discussed and the bond natures of Ln-N and Ln-O are studied by bond length linear or quadratic fitting and comparisons with relevant ionic radii. The two different C N bond distances have been simulated by the covalo-electrostatic model. (C) 2008 Elsevier Inc. All rights reserved. |
| WOS关键词 | THERMAL-DECOMPOSITION ; HEXACYANOCOBALTATE(III) TETRAHYDRATE ; SPACE GROUP ; COMPLEXES ; CRYSTAL ; HEXACYANOFERRATE(III) ; SMFE(CN)6.4H2O ; DEHYDRATION ; LN=LA ; IONS |
| 资助项目 | Hong Kong University Grants Commission Earmarked Research[102607] ; National Natural Science Foundation of China[10704090] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000266250200014 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | Hong Kong University Grants Commission Earmarked Research ; National Natural Science Foundation of China |
| 源URL | [http://119.78.100.186/handle/113462/29906]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Tanner, Peter A. |
| 作者单位 | 1.City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China 2.Chongqing Univ Post & Telecommun, Inst Modern Phys, Chongqing 400065, Peoples R China 3.Univ Hong Kong, Dept Chem, Pokfulam, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xianju,Wong, Wing-Tak,Faucher, Michele D.,et al. Crystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)(6)] center dot 4H(2)O (Ln = lanthanide)[J]. JOURNAL OF SOLID STATE CHEMISTRY,2008,181:3057-3064. |
| APA | Zhou, Xianju,Wong, Wing-Tak,Faucher, Michele D.,&Tanner, Peter A..(2008).Crystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)(6)] center dot 4H(2)O (Ln = lanthanide).JOURNAL OF SOLID STATE CHEMISTRY,181,3057-3064. |
| MLA | Zhou, Xianju,et al."Crystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)(6)] center dot 4H(2)O (Ln = lanthanide)".JOURNAL OF SOLID STATE CHEMISTRY 181(2008):3057-3064. |
入库方式： OAI收割
来源：近代物理研究所
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