Spectroscopy of High-Energy States of Lanthanide Ions
文献类型:期刊论文
作者 | Reid, Michael F.1; Hu, Liusen1,2; Frank, Sebastian1; Duan, Chang-Kui3; Xia, Shangda2; Yin, Min2 |
刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
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出版日期 | 2010-06-01 |
页码 | 2649-2654 |
关键词 | Lanthanides Rare earths Crystal field Ab initio calculations UV/Vis spectroscopy Laser spectroscopy |
ISSN号 | 1434-1948 |
DOI | 10.1002/ejic.201000182 |
英文摘要 | We discuss recent progress and future prospects for the analysis of the 4f(N-1)5d excited states of lanthanide ions in host materials. We demonstrate how ab initio calculations for Ce(3+) in LiYF(4) may be used to estimate crystal-field and spin-orbit parameters for the 4f(1) and 5d(1) configurations. We show how excited-state absorption may be used to probe the electronic and geometric structure of the 4f(N-1)5d excited states in more detail and we illustrate the possibilities with calculations for Yb(2+) ions in SrCl(2). |
WOS关键词 | RARE-EARTH IONS ; AB-INITIO CALCULATION ; CRYSTAL-FIELD ; TRIVALENT LANTHANIDES ; INORGANIC-COMPOUNDS ; CUBIC CRYSTALS ; LIYF4 CRYSTAL ; SIMPLE-MODEL ; SPECTRA ; ABSORPTION |
资助项目 | International Conference on f-Elements ; Chinese Government ; National Natural Science Foundation of China[10874173] ; National Natural Science Foundation of China[10874253] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000279975400013 |
出版者 | WILEY-V C H VERLAG GMBH |
资助机构 | International Conference on f-Elements ; Chinese Government ; National Natural Science Foundation of China |
源URL | [http://119.78.100.186/handle/113462/31693] ![]() |
专题 | 中国科学院近代物理研究所 |
通讯作者 | Reid, Michael F. |
作者单位 | 1.Univ Canterbury, Inst Adv Mat & Nanotechnol, Dept Phys & Astron & MacDiarmid, Christchurch 1, New Zealand 2.Univ Sci & Technol China, Dept Phys, Hefei 230026, Peoples R China 3.Chongqing Univ Post & Telecommun, Inst Modern Phys, Chongqing 400065, Peoples R China |
推荐引用方式 GB/T 7714 | Reid, Michael F.,Hu, Liusen,Frank, Sebastian,et al. Spectroscopy of High-Energy States of Lanthanide Ions[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2010:2649-2654. |
APA | Reid, Michael F.,Hu, Liusen,Frank, Sebastian,Duan, Chang-Kui,Xia, Shangda,&Yin, Min.(2010).Spectroscopy of High-Energy States of Lanthanide Ions.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2649-2654. |
MLA | Reid, Michael F.,et al."Spectroscopy of High-Energy States of Lanthanide Ions".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2010):2649-2654. |
入库方式: OAI收割
来源:近代物理研究所
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