Electrocatalytic oxidation of ascorbic acid by ferrocene in lipid film cast on a glassy carbon electrode
文献类型：期刊论文
| 作者 | Wang, JG; Wu, ZY; Tang, JL; Teng, RR; Wang, EK |
| 刊名 | ELECTROANALYSIS
 |
| 出版日期 | 2001-09-01 |
| 卷号 | 13页码:1093-1097 |
| 关键词 | ascorbic acids ferrocene cast film dimyristorylphosphatidylcholine |
| ISSN号 | 1040-0397 |
| 英文摘要 | A ferrocene-dimyristoyl phosphatidylcholine (DMPC) film electrode was prepared by casting the solution of ferrocene and DMPC in chloroform onto a glassy carbon electrode surface. Ferrocene retained in the biological membrane gave a couple of irreversible peaks of cyclic voltammogram. The electrode exhibited good electrocatalytic activity for the oxidation of ascorbic acid (H(2)A) in phosphate buffer (pH 6.64) with an anodic peak potential of +340 mV (vs. Ag/AgCl). The anodic current was directly proportional to the square root of the scan rate below 150 mV s(-1). The influence of the pH value was investigated and it was observed that pH 6.64 was the suitable value to the anodic peak potential and current. The thickness of the film and the interference of uric acid were also studied. The electrode can be used to determine H(2)A in the presence of equimolar uric acid. The catalytic peak current increased linearly with the concentration of H(2)A in the range of 1 X 10(-4)-5 X 10(-3) mol L-1. |
| WOS关键词 | CHEMICALLY MODIFIED ELECTRODES ; BIOMEMBRANE-LIKE FILMS |
| WOS研究方向 | Chemistry ; Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000171267200005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.186/handle/113462/37089]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Wang, EK |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Natl Analyt Res Ctr, Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China 2.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Gansu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, JG,Wu, ZY,Tang, JL,et al. Electrocatalytic oxidation of ascorbic acid by ferrocene in lipid film cast on a glassy carbon electrode[J]. ELECTROANALYSIS,2001,13:1093-1097. |
| APA | Wang, JG,Wu, ZY,Tang, JL,Teng, RR,&Wang, EK.(2001).Electrocatalytic oxidation of ascorbic acid by ferrocene in lipid film cast on a glassy carbon electrode.ELECTROANALYSIS,13,1093-1097. |
| MLA | Wang, JG,et al."Electrocatalytic oxidation of ascorbic acid by ferrocene in lipid film cast on a glassy carbon electrode".ELECTROANALYSIS 13(2001):1093-1097. |
入库方式： OAI收割
来源：近代物理研究所
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