Influence of a kind of polyanion to hybrid bilayer membranes
文献类型：期刊论文
| 作者 | Wang, JG; Teng, RR; Wang, EK |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2001 |
| 卷号 | 59页码:2138-2142 |
| 关键词 | hybrid bilayer membranes polyanions cyclic voltammetry ac impedance |
| ISSN号 | 0567-7351 |
| 英文摘要 | Hybrid bilayer membrane consisting of self-assembled alkanethiol and lipid monolayer on gold electrode was fabricated by the paint - freeze method. The interaction of a kind of polyanion, K7Fe3+P2W17O62H2 with such bilayer membrane was investigated by cyclic voltammetry and ac impedance. The hybrid bilayer membrane on the gold electrode showed remarkable insulating property, however, the property was lessened to some extent after interaction with the polyanion. It was found the process was in-eversible. It is presumed that the interaction between the polyanion and lipid is an interaction of K7Fe3+P2W17O62H2 with the polar head group of PC, which lessens the interaction among PC polar head groups. The resulting molecular arrangement becomes looser, even some pores are produced. |
| WOS关键词 | CHEMICALLY-MODIFIED ELECTRODE ; SOL-GEL TECHNIQUE ; CELL-MEMBRANES ; OXIDATION ; ELECTROCATALYSIS ; MONOLAYER ; LAYERS ; ANIONS ; CU2+ |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000172867700019 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://119.78.100.186/handle/113462/37141]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Wang, JG |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Inst Modern Phys, Lanzhou 73000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, JG,Teng, RR,Wang, EK. Influence of a kind of polyanion to hybrid bilayer membranes[J]. ACTA CHIMICA SINICA,2001,59:2138-2142. |
| APA | Wang, JG,Teng, RR,&Wang, EK.(2001).Influence of a kind of polyanion to hybrid bilayer membranes.ACTA CHIMICA SINICA,59,2138-2142. |
| MLA | Wang, JG,et al."Influence of a kind of polyanion to hybrid bilayer membranes".ACTA CHIMICA SINICA 59(2001):2138-2142. |
入库方式： OAI收割
来源：近代物理研究所
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