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Fabrication and thermal stability of two-dimensional carbide Ti3C2 nanosheets

文献类型:期刊论文

作者Wang, Kun1,2; Zhou, Youfu1; Xu, Wentao1; Huang, Decai1; Wang, Zhiguang3; Hong, Maochun1
刊名CERAMICS INTERNATIONAL
出版日期2016-05-15
卷号42页码:8419-8424
关键词Thermal stability Two-dimensional Ti3C2 MXene MAX phases
ISSN号0272-8842
DOI10.1016/j.ceramint.2016.02.059
英文摘要Two-dimensional Ti3C2 nanosheets were obtained by exfoliation of synthesized Ti3AlC2 powders in 40% HF solution at room temperature. The influence of etching time on the synthesis, structural evolution during heating, and thermal stability of as-prepared Ti3C2 nanosheets were studied. The graphene-like structure of as-prepared Ti3C2 nanosheets was confirmed by XRD and SEM. TG-DTA and elemental analysis suggested that the OH and F groups attached on the surface of Ti3C2 nanosheets could be eliminated by heat treatment. It is noteworthy that Ti3C2 nanosheets are thermal stable up to 1200 degrees C in Ar atmosphere. In the heating process, a small quantity of TiO2 anatase emerges at 500 degrees C and then reacts with Ti3C2 to form a solid solution of TiCxO1-x (0 < x < 1) with the increase of temperature. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
WOS关键词LITHIUM-ION BATTERIES ; TRANSITION-METAL CARBIDE ; TITANIUM CARBIDE ; MXENE TI3C2 ; MAX PHASES ; ANODE ; GRAPHENE ; LI ; SUPERCAPACITOR ; INTERCALATION
资助项目CAS Priority Research program[XDA03010301] ; State Key Laboratory of New Ceramic and Fine Processing Tsinghua University[KF201517] ; Natural Science Foundation of Fujian Province[2014H0055]
WOS研究方向Materials Science
语种英语
WOS记录号WOS:000374075300070
出版者ELSEVIER SCI LTD
资助机构CAS Priority Research program ; State Key Laboratory of New Ceramic and Fine Processing Tsinghua University ; Natural Science Foundation of Fujian Province
源URL[http://119.78.100.186/handle/113462/42282]  
专题中国科学院近代物理研究所
通讯作者Zhou, Youfu
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Inst Modem Phys, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Wang, Kun,Zhou, Youfu,Xu, Wentao,et al. Fabrication and thermal stability of two-dimensional carbide Ti3C2 nanosheets[J]. CERAMICS INTERNATIONAL,2016,42:8419-8424.
APA Wang, Kun,Zhou, Youfu,Xu, Wentao,Huang, Decai,Wang, Zhiguang,&Hong, Maochun.(2016).Fabrication and thermal stability of two-dimensional carbide Ti3C2 nanosheets.CERAMICS INTERNATIONAL,42,8419-8424.
MLA Wang, Kun,et al."Fabrication and thermal stability of two-dimensional carbide Ti3C2 nanosheets".CERAMICS INTERNATIONAL 42(2016):8419-8424.

入库方式: OAI收割

来源:近代物理研究所

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