Luminescence and crystal field analysis of Eu3+ in Eu[Co(CN)(6)]center dot 4H(2)O
文献类型：期刊论文
| 作者 | Zhou, Xianju; Duan, Chang-Kui; Tanner, Peter A. |
| 刊名 | JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
 |
| 出版日期 | 2007-10-01 |
| 卷号 | 68页码:1921-1925 |
| 关键词 | inorganic compounds infrared spectroscopy crystal field luminescence phonons |
| ISSN号 | 0022-3697 |
| DOI | 10.1016/j.jpcs.2007.05.023 |
| 英文摘要 | The vibrational spectra of Eu[Co(CN)(6)]center dot 4H(2)O and luminescence spectra of Eu3+ in this compound, using 355 nm excitation at temperatures down to 10 K, have been assigned. A clear distinction is made between the n = 5 and 4 members of the Ln[M(CN)(6)] center dot nH(2)O series from the vibrational spectra. The electronic spectra show prominent vibronic structures, particularly for the (5) D0 -> F-7(1) sideband. A resonance occurs between the transitions D-5(0)-> F-7(1)(III) and D-5(0)-> F-7(0) + v(Eu-N). A crystal field analysis of the derived energy data set is presented for Eu3+ in eight coordination geometry. (c) 2007 Elsevier Ltd. All rights reserved. |
| WOS关键词 | SINGLE-CRYSTAL ; STRUCTURAL REFINEMENT ; THERMAL-DECOMPOSITION ; LANTHANIDES ; DEHYDRATION |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000250654200016 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.186/handle/113462/46667]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Tanner, Peter A. |
| 作者单位 | 1.City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Hong Kong, Peoples R China 2.Chongqing Univ Post & Telecommun, Inst Modern Phys, Chongqing 400065, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xianju,Duan, Chang-Kui,Tanner, Peter A.. Luminescence and crystal field analysis of Eu3+ in Eu[Co(CN)(6)]center dot 4H(2)O[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,2007,68:1921-1925. |
| APA | Zhou, Xianju,Duan, Chang-Kui,&Tanner, Peter A..(2007).Luminescence and crystal field analysis of Eu3+ in Eu[Co(CN)(6)]center dot 4H(2)O.JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,68,1921-1925. |
| MLA | Zhou, Xianju,et al."Luminescence and crystal field analysis of Eu3+ in Eu[Co(CN)(6)]center dot 4H(2)O".JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 68(2007):1921-1925. |
入库方式： OAI收割
来源：近代物理研究所
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