Synchrotron excitation, emission and theoretical simulation of lanthanide ions in hexachloroelpasolite crystals
文献类型：期刊论文
| 作者 | Duan, Chang-Kui1,2; Tanner, Peter A.2; Meijerink, Andries3; Babin, Vladimir3 |
| 刊名 | JOURNAL OF PHYSICS-CONDENSED MATTER
 |
| 出版日期 | 2009-09-30 |
| 卷号 | 21页码:8 |
| ISSN号 | 0953-8984 |
| DOI | 10.1088/0953-8984/21/39/395501 |
| 英文摘要 | Emission and excitation spectra of Cs(2)NaLnCl(6) (Ln = Y, Eu, Gd, Er, Yb), Cs2NaYCl6: Ce and Cs2NaYCl6: Tm have been recorded using synchrotron radiation. With the possible exception of the case for Ce3+, no 5d -> 4f transitions are observed and the emission spectra are entirely assigned to 4f -> 4f intraconfigurational transitions of Ln(3+) in LnCl(6)(3-) and impurity species. The excitation spectra comprise intraconfigurational, charge transfer and band-to-band transitions. Trace impurities of oxy-species or of other lanthanide ions have a profound effect upon the spectra. The 4f-5d absorption spectra have been simulated by employing the suite of programs of Professor M F Reid and the results have been included together with the experimental spectra. |
| WOS关键词 | ELECTRONIC-SPECTRA ; HEXAFLUOROELPASOLITE LATTICES ; CONFIGURATION-INTERACTION ; ENERGY-LEVELS ; ELPASOLITE ; LUMINESCENCE ; TRANSITIONS ; ABSORPTION ; SPECTROSCOPY ; TM3+ |
| 资助项目 | Hong Kong Research grants Council General Research Fund[CityU 102308] ; National Science Foundation of China[10874253] |
| WOS研究方向 | Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000269626500007 |
| 出版者 | IOP PUBLISHING LTD |
| 资助机构 | Hong Kong Research grants Council General Research Fund ; National Science Foundation of China |
| 源URL | [http://119.78.100.186/handle/113462/46693]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Duan, Chang-Kui |
| 作者单位 | 1.Chongqing Univ Post & Telecommun, Inst Modern Phys, Chongqing 400065, Peoples R China 2.City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China 3.Univ Utrecht, Dept Chem, Debye Inst, NL-3584 CH Utrecht, Netherlands |
| 推荐引用方式 GB/T 7714 | Duan, Chang-Kui,Tanner, Peter A.,Meijerink, Andries,et al. Synchrotron excitation, emission and theoretical simulation of lanthanide ions in hexachloroelpasolite crystals[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2009,21:8. |
| APA | Duan, Chang-Kui,Tanner, Peter A.,Meijerink, Andries,&Babin, Vladimir.(2009).Synchrotron excitation, emission and theoretical simulation of lanthanide ions in hexachloroelpasolite crystals.JOURNAL OF PHYSICS-CONDENSED MATTER,21,8. |
| MLA | Duan, Chang-Kui,et al."Synchrotron excitation, emission and theoretical simulation of lanthanide ions in hexachloroelpasolite crystals".JOURNAL OF PHYSICS-CONDENSED MATTER 21(2009):8. |
入库方式： OAI收割
来源：近代物理研究所
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